ABSTRACT Michael John Kirkland. PETROLOGY AND DIAGENESIS OF SANDSTONES OF THE BLUEFIELD FORMATION (UPPER MISSISSIPPIAN), SOUTHEAST WEST VIRGINIA. (Supervising Professor, Dr. Donald W. Neal), Department of Geology, December, 1985. The Bluefield Formation comprises interbedded shales, limestones and sandstones representing deposition transitional between marine carbonates and shallow marine to deltaic siliclclastics. Bluefield sandstones vary lithologically from relatively coarse-grained, clean, and orthoquartzltic (up to 95.0% quartz) to very fine-grained, matrix- and rock fragment-rich (as low as 41.0% quartz) varieties. In this study, sandstones are subdivided into two groups: Type 1, which are very fine-grained and argillaceous; and Type 2, which are coarse-grained, clean, and quartzitic. Diagenetic alteration of Type 1 sandstones was dominated by mechanical compaction. Quartz authigenesis, accompanied by intergranular pressure solution, was the principal diagenetic process in Type 2 sands. Minor secondary porosity is present in Type 1 sands. Type 2 sandstones contain small amounts of both primary and secondary porosity. The lower part of the Bluefield Formation consists of marine limestones, calcareous shales and thin, carbonate-cemented shelf sands deposited in a shallow marine setting. The Droop Sandstone, located approximately at the boundary between the upper and lower Bluefield, was deposited as a prograding barrier island complex. Upper Bluefield strata were deposited in a prograding delta. PETROLOGY AND DIAGENESIS OF SANDSTONES OF THE BLUEFIELD FORMATION (UPPER MISSISSIPPIAN), SOUTHEAST WEST VIRGINIA A Thesis Presented to the Faculty of the Department of Geology East Carolina University In Partial Fulfillment of the Requirements for the Degree Master of Science in Geology by Michael John Kirkland December, 1985 PETROLOGY AND DIAGENESIS OF SANDSTONES OF THE BLUEFIELD FORMATION (UPPER MISSISSIPPIAN), SOUTHEAST WEST VIRGINIA by Michael John Kirkland APPROVED BY: COMMITEE CHAIRMAN OF DEAN OF THE GRADUATE SCHOOL ACKNOWLEDGEMENTS Partial funding for this study was provided by a grant-in-aid from the Sigma Xi Scientific Research Foundation. I would like to express my thanks to Dr. Donald Neal for his guidance during the preparation of this thesis. Thanks go also to Dr. Charles Q. Brown, Dr. Scott Snyder and Dr. Floyd Read for their many helpful suggestions while serving as committee members. I particularly wish to express my appreciation to my parents for their patience, understanding and moral support. TABLE OF CONTENTS PAGE INTRODUCTION 1 PURPOSE 2 LOCATION 2 GEOLOGIC SETTING 2 METHODS 7 SUBDIVISION OF SANDSTONES 11 TYPE 1 SANDSTONES 15 CLASSIFICATION 15 GRAIN SIZE 18 PETROGRAPHY 18 Quartz 18 Rock Fragments 19 Feldspars 20 Carbonate 21 Accessory Minerals 21 Matrix 22 DIAGENESIS OF TYPE 1 SANDSTONES 24 MECHANICAL COMPACTION 24 CARBONATE CEMENTATION 25 IRON MINERALS 29 PRESSURE SOLUTION FEATURES 32 AUTHIGENIC CLAY MINERALS. . 36 TYPE 2 SANDSTONES 37 CLASSIFICATION 37 GRAIN SIZE 37 PETROGRAPHY 39 Quartz 39 Rock Fragments 40 Feldspars 40 Carbonate 41 Accessory Minerals 42 Matrix 43 DIAGENESIS OF TYPE 2 SANDSTONES 44 MECHANICAL COMPACTION 44 POROSITY 45 CARBONATE 47 HEMATITE 50 CLAY MINERALS 52 QUARTZ AUTHIGENESIS 54 Summary 61 STYLOLITES AND FRACTURES 62 DIAGENETIC SEQUENCE 64 EARLY STAGE OF DIAGENESIS 64 MIDDLE STAGE OF DIAGENESIS 66 LATE STAGE OF DIAGENESIS 67 SUMMARY 68 DEPOSITIONAL SETTING 70 GENERAL 70 PROVENANCE 70 PREVIOUS INVESTIGATIONS 72 DEPOSITIONAL ENVIRONMENTS 75 LOWER SANDSTONES 75 DROOP SANDSTONE 78 UPPER SANDSTONES 80 Introduction 80 Indian Mills Sandstone 81 Bradshaw Sandstone 83 Bertha Sandstone 84 Graham Sandstone 86 Clayton Sandstone 87 Summary 88 DISCUSSION 89 Basin Energy 89 Conclusions 91 SUMMARY 93 REFERENCES CITED 95 APPENDIX A: MEASURED SECTIONS 100 General 100 1) Red Sulphur Springs Section 101 2) Buck Section 103 3) Talcott (1) Section 104 4) Marie Section 105 5) Bertha Section 106 6) Big Bend Section 107 7) Pence Springs Section 108 8) Rock Camp Section 109 9) Talcott (2) Section 110 10) Alderson Section Ill 11) Alta Section 112 12) Assurance Section 113 13) Wayside Section 114 14) Greenville Section 115 APPENDIX B: DATA 116 1) POINT COUNT DATA 116 2) GRAIN SIZE DATA 119 LIST OF ILLUSTRATIONS FIGURES PAGE 1. Location map of study area 3 2. Generalized stratigraphic section for the Upper Mlssissippian of southeastern West Virginia 4 3. Classification scheme used for Bluefleld Formation sandstones 10 4. Quartz percentage vs grain size for Bluefield Formation sandstones 13 5. Classification of Type 1 Bluefleld Formation sandstones showing all samples 16 6. Classification of outcrops of Bluefield sandstones 17 7. Classification of Type 2 Bluefield Formation sandstones. . . 38 8. Sequence of dlagenetic events 65 9. Upper Mlssissippian (Chesterlan) paleogeography 71 10. Summary of upper Bluefleld sandstone depositional environments 90 TABLES 1. Sample sites 8 2. Major deltaic depositional environments 82 PLATES 1: Typical development of Type 1 sandstone 14 2: Typical development of Type 2 sandstone 14 3: Carbonate grain with calcite core and dolomite rim in Type 1 sandstone 26 4: Ovoid in lower Bluefield sandstone largely cemented by quartz 28 5: Euhedral hematite with pyrite core 31 6: "Stylolitic seam" and "solution seam" in Type 1 sandstone. . . 34 7: Primary intergranular porosity in Type 2 sandstone 46 8: Moldlc porosity formed through partial dissolution of feldspar in Type 2 sandstone 48 9: Carbonate replacement of feldspar 49 10: Carbonate-cemented Type 2 sand 51 11: Authigenic clay surrounding quartz grain and between quartz grain and its overgrowth 53 12: "Quartz enlargement" vs pressure solution in Type 2 sandstone. 55 13: Grain coatings, Incomplete overgrowths and moldic porosity in Type 2 sandstone 56 14: Incomplete quartz overgrowth 58 INTRODUCTION The Bluefield Formation, at the base of the Upper Mississippian Mauch Chunk Group in West Virginia, is a marginal marine deposit transitional between the underlying marine Greenbrier Limestone and overlying shallow marine to deltaic sediments of the upper Mauch Chunk Group and Pennsylvanian System. The Bluefield Formation is composed of intercalated sandstone, shale, limestone and minor coal. West Virginia Geological Survey reports indicate eight prominent sandstone bodies, some of which are natural gas producers. From oldest to youngest, they are the Edray, Webster Springs, Droop, Indian Mills, Bradshaw, Bertha, Graham, and Clayton Sandstones. They vary from greenish-gray to buff, fine- to very fine-grained, calcareous varieties in the lower part of the Bluefield to greenish-gray and reddish-brown, fine- to very fine-grained varieties in its upper parts. The distinctive Droop Sandstone, located at the transition between upper and lower parts of the Bluefield Formation, is coarse-grained, white, and cross-bedded. These sandstones have been briefly described in West Virginia Geological Survey County Reports (Reger, 1926; Price and Heck, 1939; Price, 1939), but descriptions are restricted to color, characteristic bedding and grain size, and thickness. Other references to the Bluefield are found as part of a general overview of Mississippian stratigraphy (Englund, 1979; Arkle and others, 1979). McColloch (1957), Manspeizer (1958) and Humphreville (1981) dealt with stratigraphic and paleontological aspects of the Bluefield Formation. However, detailed studies of the texture, mineralogy, and diagenetic histories of Bluefield sandstones are 2 lacking. PURPOSE An investigation of Bluefield outcrops was undertaken in order to accomplish the following objectives: 1) determine composition and textures of the sandstones; 2) characterize diagenesis within the sandstones; 3) interpret the depositional environments; and 4) evaluate compositional, textural, and diagenetic changes relative to depositional environments and stratigraphic position. LOCATION The study area encompasses Monroe, Summers, and part of southern Greenbrier Counties, West Virginia (Fig. 1). It is located within the Appalachian Plateau physiographic province, a rugged and mountainous area dissected by numerous streams which have created V-shaped eroslonal valleys. Maximum relief for the area is 955 meters. The three counties encompass a total of 4829 square kilometers (Reger, 1926). GEOLOGIC SETTING Rocks of the study area crop out in a band of horizontal to gently northwestwardly dipping strata that form part of a northeast trending monoclinal structure (Arkle and others, 1979). The Bluefield Formation is underlain by the Greenbrier Group and is overlain by the Hinton Formation (Figure 2). The Greenbrier Group ranges to a maximum thickness of 550 meters in 3 Figure 1. Location map: Summers, Monroe and Greenbrier Counties, West Virginia showing location of sections (after Cardwell and others, 1968). The striped area shows the outcrop of the Bluefield Formation. 4 Figure 2. Generalized stratigraphic section for the Upper Misslsslpplan of southeastern West Virginia (after Reger, 1926; Arkle and others, 1979). 5 Mercer County, West Virginia, and thins northwestwardly to a minimum of 15 meters. It consists predominantly of cherty, argillaceous, sandy and oolitic limestone with some interbedded shale (Arkle and others, 1979); and it was deposited in a shallow open marine setting (Englund, 1979). The Bluefleld Formation is composed of intercalated gray and green shale, limestone, and sandstone with minor red shale in its lower part; and green, gray and red sandstone and shale with minor limestone and coal in its middle and upper portions (Arkle and others, 1979; Reger, 1926). It reaches its maximum thickness of 400 meters in Mercer County, West Virginia, and thins to the north and northwest. This is due partly to stratigraphic convergence and partly to Early Pennsylvanian erosional truncation. This same thickness trend holds for all Mlssissippian rocks in the region, but erosion is a factor mainly in the upper part of the Mlssissippian (Arkle and others, 1979; Youse, 1964). The Bluefleld was deposited largely under nearshore marine conditions in a shallow, slowly subsiding basin (Arkle and others, 1979; Englund, 1979; Whisonant and Scolaro, 1979; Humphreville, 1981). Depositonal environments represented by Bluefleld strata range from normal marine carbonates to nearshore muds, sands, and freshwater marshes deposited in a system Influenced by tidal energy (Whisonant and Scolaro, 1979; Humphreville, 1981). The Hinton Formation is composed of interbedded red, partly calcareous shale and siltstone, ferrugenous and calcareous sandstone, fossil-bearing limestone and minor coal (Arkle and others, 1979). It represents shallow marine, barrier bar, tidal flat and fresh-water marsh environments (Craig and Varnes, 1979; Hobday and Horne, 1979; Colton, 6 1970). The main structural feature in the study area is the St. Clair thrust fault. It extends from Allegheny County, Virginia southward at least to Richlands, Virginia (Gwlnn, 1964), and it represents the major structural boundary separating the gently folded Appalachian Plateau Province from the more extensively deformed Valley and Ridge Province (Rogers, 1963). Another important feature in the area is the Hurricane Ridge Syncline, described by Reger (1926) in both Mercer and Monroe Counties, West Virginia, with the St. Clair Fault forming the eastern margin of the syncline (Fig. 1). McDowell (1982) separated the Hurricane Ridge Syncline of Reger into the Glen Lyn, Hurricane Ridge, and Caldwell Synclines. He defined the Glen Lyn as the overturned syncline which runs parallel and adjacent to the St. Clair Fault. The Hurricane Ridge Syncline is found in southern Mercer County, West Virginia. The Caldwell is a broad, open fold extending northward from central Monroe County, West Virginia (Fig. 1). McDowell considers this to be an extension of the Caldwell Syncline of Price and Heck (1939). In addition, Reger (1926) mapped the Abbs Valley Anticline throughout Mercer and Monroe Counties, West Virginia, but McDowell (1982) stated that this anticline extends only to Mercer County and is not found in Monroe County. Elsewhere in Monroe and Summers Counties, West Virginia, Reger (1926) named numerous anticlines and synclines, the limbs of which dip on the order of a few degrees. Folds extending from northern Monroe County north into Greenbrier County become more more steeply dipping. 7 METHODS Nineteen sandstone outcrops from 14 localities were measured, described, and sampled for this study (Fig. 1). They were chosen according to accessibilty and completeness of section. Samples were taken to best represent the dominant lithology and any variations in lithology (Table 1). Ninety—five thin sections were examined, 82 of which were point-counted to determine mineralogy by identifying 300 grains along a traverse normal to bedding. Average grain size was determined by measuring the apparent long axes of 100 quartz grains per thin section. Quartz alone was used in order to eliminate bias. X-ray diffraction analysis (XRD) utilized uncovered thin sections and whole-rock oriented slides. All thin sections were examined via XRD to determine the composition of carbonate (where present) and presence or absence and type of feldspars. This analysis also aided in determination of clay mineralogy. Twenty samples, selected to best represent dominant lithologies within Bluefield sandstones, were crushed, wetted, and allowed to settle on glass slides in order to enhance basal clay reflections. These oriented slides were used to further analyze the clay mineralogy. A modified version of Folk's 1974 sandstone classification scheme is used for this study. The basic method and format is retained for those rocks that are relatively clean (matrix less than 10%). Rocks with more than 10% matrix are treated similarly to Dott's 1964 classification but superimposed on Folk's basic format. For example, a 8 TABLE 1 Section Sandstone Outcrop Sand- Number Number stone Samples Thin Type Sections 1-Red Sulpher Clayton la 1 7 2 Springs Graham lb 1 6 2 Bradshaw Ic 1 6 2 Indian Mills Id 1 5 2 2-Buck Clayton 2a 1 10 2 Graham 2b 2 17 10 3-Talcott #1 Clayton 3a 1 9 2 Bertha 3b 1 4 2 4-Marie Bertha 4 mixed 14 7 5-Bertha Bertha 5 mixed 13 6 6-Big Bend Bradshaw 6 mixed 15 8 7-Pence Springs Bradshaw 7 1 6 4 8-Rock. Camp Indian Mills 8 2 14 6 9-Talcott #2 Droop 9 2 15 .8 10-Alderson Droop 10 2 34 8 11-Alta Droop 11 2 22 7 12-Assurance Webster Springs 12 1 7 4 13-Wayside Webster Springs 13 1 11 9 14-Greenville Ed ray? 14 1 4 4 219 95 9 litharenlte under Folk's classification with greater than 10% matrix is called a llthic wacke (Fig. 3). 10 0 o Figure 3: Classification scheme used for Bluefield Formation sandstones (after Dott, 1964 and Folk, 1974). Q represents quartz, F, feldspar and R, rock fragments. 11 SUBDIVISION OF SANDSTONES The sandstones of this study represent the coarser-grained detrital units of the Bluefield Formation. Based on compositional and textural criteria, including grain size, petrography, and outcrop development, they have been divided into two groups, termed Type 1 and Type 2 sandstones. Outcrops of Type 1 sandstones, the most common type. tend to be (10 to 20 feet). In outcrop. Type 1 sandstones are generally green, red, or mixed green and red on fresh surfaces, shaly to flaggy and occasionally massive, and ripple-marked. Most are shaly towards their base and have a gradational lower contact. Coarsening upward sequences are common, the uppermost beds ranging from flaggy to massive with a sharp upper contact. Type 2 sandstones, which contain the coarsest-grained detritus within the Bluefield, occur in thicker exposures (greater than 20 feet) of its sand members. In outcrop, they are thick-bedded and coarse-grained and range from flat-bedded to cross-bedded to massive. Cross-bedding is typically medium- to large-scale and high angle. Both planar and trough cross-bedding are present. Most Type 2 sandstones are white to buff in color but may, in part, be greenish or brownish. Typically, they are composed of coarse-grained, clean sand but may have shale interbeds or lenses. No fining or coarsening trends are noticeable in outcrops composed entirely of Type 2 sandstone; however, fining upward sequences can be recognized in thin section. Type 2 sandstones are best represented by the Droop Sandstone which 12 provides three of the five outcrops (9, 10, and 11) that are composed entirely of Type 2 sandstone. Only two other outcrops (2b and 8) are composed entirely of Type 2 sandstone. These outcrops represent localized areas of thickening and coarsening within the Graham and Indian Mills Sandstones, respectively. Three outcrops (4, 5, and 6) contain both Type 1 and Type 2 sandstone intervals. The basal portion of outcrop 4 (Bertha Sandstone) is composed of Type 2 sandstone which fines upward into Type 1 sandstone. Outcrop 5 (Bertha Sandstone) includes Type 2 sandstone at the top and bottom of the outcrop,- between which there is Type 1 sandstone. Outcrop 6 (Bradshaw Sandstone) is composed of intercalated Type 1 and Type 2 sandstones with minor limestone and shale interbeds. Figure 4 is a plot of quartz percentage vs grain size for all samples in this study. The line on the diagram separates Type 1 from Type 2 sandstones. Type 2 sandstones are coarser-grained and richer in quartz than Type 1 sandstones. The dividing line was drawn visually and is somewhat arbitrary, serving primarily for descriptive purposes. Note that quartz percentage varies dramatically in Type 1 sandstones, whereas grain size, and not quartz percentage, varies widely in Type 2 sandstones. Other differences are associated with this subdivision. Type 1 sandstones are generally more mineralogically diverse and are typically richer in matrix, rock fragments, feldspar, carbonate and accessory minerals. Type 2 sandstones are richer in quartz, cleaner (better washed), better sorted, and constituents are better rounded than Type 1 sandstones. Typical examples of Type 1 and Type 2 sandstones, as seen in thin section, are shown in Plates 1 and 2, respectively. 13 Figure 4: Quartz percentage vs grain size. Type 2 sandstones are to the right of the line; Type 1 sandstones are to the left of the line. Circles indicate multiple samples. 14 Plate 1: Typical development of Type 1 sandstone (crossed nichols, 25x). Plate 2: Typical development of Type 2 sandstone (crossed nichols, 25x). 15 TYPE 1 SANDSTONES CLASSIFICATION Individual samples of Type 1 (fine-grained, impure) sandstones are plotted on a ternary QFR diagram in Figure 5. Data for this diagram are listed in Appendix B. Outcrops 4 and 5 of the Bertha Sandstone and outcrop 6 of the Bradshaw Sandstone contain samples of both Type 1 and Type 2 sandstone which are plotted on Figures 5 and 7, respectively. More than half of the samples of Type 1 sandstone are litharenites or lithlc wackes, which are, in turn, approximately even in number. The remainder are sublitharenltes or sublithic wackes with the exception of one quartzarenite. This sample, as well as those that plot at the quartz-rich end of the sublitharenlte region, is high in either matrix, carbonate or a combination of both constituents. All but three of the samples which fall in the sublitharenite/sublithic wacke and quartzarenite regions are from sandstones in the lower part of the Bluefield (Webster Springs and Edray Sandstones). The averages for each outcrop of Type 1 sandstone are plotted in Figure 6. Most outcrops are lithic wackes or litharenites. Outcrops 13 and 14 (lower Bluefield sandstones), however, plot as sublitharenlte and sublithic wacke, respectively. The grand mean of Type 1 sandstones falls near the quartz-rich end of the lithic wacke range. Outcrops 4 and 5 of the Bertha Sandstone and outcrop 6 of the Bradshaw Sandstone are composed of both Type 1 and Type 2 sandstone. Similar samples from these outcrops are grouped, averaged and plotted together in Figure 6. Therefore each of these outcrops is represented by 2 plots, one 16 Quartz Fragments Figure 5: Classification of Type 1 Bluefield Formation sandstones showing all samples. Arenites (less than 10% matrix) are symbolized as dots. Wack.es (greater than 10% matrix) are shown with an "x". 17 Quartz Fragments Figure 6: Classification of outcrops of Bluefield sandstones. Numbers refer to outcrops. Arenites (less than 10% matrix) are symbolized as dots. Wackes (greater than 10% matrix) are shown with an "x". 18 representing Type 1, and one representing Type 2 components within each sandstone. GRAIN SIZE Type 1 sandstones range from medium silt to very fine sand as measured in thin section. Calculated grain size averages for all but one Type 1 sandstone outcrop fall in the coarse silt size range. All are composed of both silt and sand interbeds. Approximately half (outcrops 2a, Ic, 7, 12 and 14) are dominated by sand interbeds and the calculated coarse silt grain size is due to sampling bias. Remaining Type 1 outcrops (outcrops la, lb, 3b, Id, and 13) are dominated by silt interbeds and represent siltstone horizons of the sandstones. Calculated grain size averages for outcrops which contain both Type 1 and Type 2 sandstone interbeds (outcrops 4, 5 and 6) fall in the very fine sand range; but they contain rocks ranging from coarse silt to fine sand. PETROGRAPHY Quartz The most abundant detrital constituent in Type 1 sandstones is quartz. The mean for all samples is 55.8% and the range is from 41.0% to 71.7%. Grain shape varies from subround to angular and most grains possess low sphericity. Most grains are monocrystalline with straight to slightly undulóse extinction. Polycrystalline grains and grains with strongly undulóse extinction are rare. Quartz grain size is generally uniform throughout a given sample, but many samples consist of 19 interlayered quartz-rich and phyllosilicate-rich intervals. Most grains are clear and lack Inclusions. Vacuoles and inclusions (e.g., rutile) are present in trace amounts. Rock Fragments Rock fragments, the second most abundant constituent in Type 1 sandstones, are predominantly metamorphic rock fragments (MRFs). Rock fragments range from 0.0% to 43.7% and average 21.5%. MRFs range from 0.0% to 30.0% and average 18.3%. MRFs consist of slate, phyllite and schist fragments, with phyllite fragments predominating. They are distinguished from sedimentary rock fragments (SRFs) by the orientation of clays and/or the large size and parallel orientation of micas within the fragments. The most abundant mica within the MRFs is muscovite, followed by biotite, chlorite and undifferentiated micas. Chlorite schist fragments are present in small amounts and are distinguished by their color. MRFs are typically elongate, with their long axes usually greater than those of associated quartz grains. SRFs range from 0.0% to 30.7% and average 3.2%. SRFs consist of shale fragments, rare chert, and very rare siltstone clasts. They are distinguished from MRFs by lack of orientation of their constituent clays. Many grains are gradational between MRF and SRF. Some orientation may occur in SRFs due to extremely low energy during deposition, or due to diagenetic alteration during lithlfication. Most SRFs are well-rounded, equant to elongate, and are often somewhat larger than surrounding quartz grains. Rlp-up clasts are also present. These 20 clasts are often very large relative to other constituents (typically 2 to 3 mm, but up to 1cm in length); they are typically elongate and highly angular, indicating very short transport distances, and hence are considered intrabasinal. Deformation of both MRFs and SRFs is very extensive in some cases. This feature has been called pseudomatrix (Scholle, 1979). This phenomenon, plus the fine-grained nature of these samples, makes the precise differentiation of rock fragments and matrix difficult. Feldspars Feldspar percentages, as measured by point count, range from a trace to 5.3%, and average 1.0%. Feldspar grains are typically equant to somewhat elongate, and vary from rounded to subangular. Plagioclase was the only type of feldspar encountered during microscopic examination. Using the Michel-Levy method to estimate composition, grains appear to be high sodium plagioclase (oligoclase or perhaps higher). Uncovered thin sections were examined by X-ray diffractoraetry. In almost every case, plagioclase is indicated by the X-ray pattern. It is generally believed that plagioclase must make up at least 5% of a given sample in order to register on an X-ray pattern (Carroll, 1970). Point count data may, therefore, underrepresent feldspar. Staining of selected samples for plagioclase and potassium feldspar yielded negative results, indicating that no potassium feldspar is present. The stain for plagioclase requires the presence of calcium in the feldspar structure, thus high sodlc-low calcic plagioclase does not stain. Therefore, plagioclase in these samples is considered to be highly 21 sodio. Plagioclase may be overlooked during optical examination due to lack of twinning, lack of alteration, small size, or Inclusion within rock fragments. Alteration of feldspars within Type 1 sandstones is variable. Much of the feldspar is clear, but some is cloudy due to varying degrees of alteration, generally kaolinitization. The degree of alteration often varies widely within a given sample, probably due to compositional differences or variations in microporosity. Carbonate Carbonate occurs in most Type 1 sandstones, ranging from 0.0% to 48.3% among samples, from 0.0% to 20.9% within the individual sandstones (i.e., the averages for individual sandstones), and averaging 4.0% overall. Dolomite, the predominant carbonate mineral, appears to be secondary after calcite. Traces of high-Mg-calclte are present. Carbonate occurs as large pore-filling, occasionally polkiolitlc grains and as a granular matrix-like texture. Calcite occurs as large pore-filling grains while dolomite occurs both as large grains and as a granular matrix-like texture. Carbonate grains are clear and unaltered or partly to wholly stained or replaced by hematite. Accessory Minerals Accessory minerals found in Type 1 Bluefleld sandstones include muscovite, biotite, chlorite, hematite, pyrite, zircon, tourmaline, rutile and opaques. Together they constitute from a trace to 13.3% and average 3.8% of Type 1 sandstones. The micas (muscovite, biotite, and 22 to a lesser extent chlorite) are the most abundant of these minerals in most samples. Occasionally, hematite and, more rarely, opaques predominate. The micas are elongate and usually bent or kinked due to compaction. They occur as randomly distributed grains, but coarse-grained micas are often concentrated along bedding planes. Fine-grained micas associated with MRFs and clay minerals are concentrated into zones alternating with quartz-rich zones. Hematite is found as a stain, grain coatings, pore-filling cement, along stylolites, in association with carbonate as a replacement mineral, as fracture-fill, and as large subhedral to euhedral crystals which may be pseudomorphic after pyrite. Pyrite is found in only a few samples where it forms large euhedral crystals. In a few samples it is found as shapeless masses, or as pyrite framboids. In one sample it is found filling circular pores within a plant fossil. Zircon is ubiquitous in trace amounts. Grains are typically small, well-rounded and highly spherical to slightly elongate. A minor fraction is larger, more elongate, and often exhibits euhedral terminations. Well-rounded, highly spherical, blue and green pleochrolc tourmaline is present in trace amounts. Some types of accessory minerals are found concentrated along bedding planes. Matrix Matrix material ranges from 0.0% to 28.7% and averages 13.7% of Type 1 sands. Matrix Includes very fine-grained material (approximately 0.02mm or less) and grains without definite shape. Shapeless material includes deformed grains, a feature called pseudomatrix (Scholle, 1979). 23 Pseudomatrix occurs during compactional deformation when softer grains, such as SRFs and low grade MRFs, are squeezed into the interstices between harder grains such as quartz (Scholle, 1979). Thus, matrix includes pseudomatrix, detrltal clays, authlgenic clays, and fine-grained and/or shapeless material. Matrix is often stained by iron oxide (hematite) which severely hampers differentiation. 24 DIAGENESIS OF TYPE 1 SANDSTONES Diagenetic alteration of Type 1 (fine-grained) Bluefield sandstones takes the form of reduction or occlusion of primary porosity through mechanical compaction, carbonate cementation, hematite cementation, and pressure solution. Porosity reduction due to growth of authigenic clay also occurred. Stylolltes are common in these sandstones. Rare secondary porosity is present in the form of raoldic and fracture porosity. MECHANICAL COMPACTION Mechanical compaction was the most important process in lithifIcation and occlusion of primary porosity in Type 1 sandstones. This is evidenced by the distortion of labile fragments (MRFs, SRFs, and micas), which are typically bent or kinked at one or more points along their lengths. The compression squeezes portions of the relatively soft labile grains into the interstices between more rigid grains (largely quartz), thereby filling pore space and affecting lithlfication. Some labile grains were so distorted as to obscure their original character, creating pseudomatrix. Larger grains, particularly the large micas, appear to have undergone greater amounts of distortion than smaller grains. Compaction was particularly effective in reducing porosity and enhancing lithlfication in samples with high percentages of labile grains. Plagioclase grains also show signs of deformation. Occasional grains were fractured and separated parallel to twin planes, while others were kinked at high angles to twin planes. 25 Fractures are common in Type 1 sandstones. Most are oriented parallel to bedding; but a few are oriented at high angles to bedding, probably due to overburden stress (i.e., vertically oriented compressive stress causes horizontal tenslonal strain and fracturing). Fractures oriented parallel to bedding are most likely caused by release of overburden stress. CARBONATE CEMENTATION Carbonate cementation is common in Type 1 sandstones. It is found largely as pore-filling cement in clean, quartz-rich samples, but is also found in oversized pores, randomly distributed "patches" and as fracture-fill cement. The pore-filling carbonate cement and the carbonate found in random patches is mostly dolomite, with lesser amounts of calcite; although in some samples calcite is more abundant than dolomite. Trace amounts of high-Mg-calcite are also present. Calcite usually occurs as remnants within dolomite, suggesting dolomitization of an original calcite cement (Plate 3). Dolomitization may have occurred due to migration of Mg-rich fluids derived from diagenesis of clays in associated shales or from within the sandstones themselves. Permeabilities in calcitic zones, however, may have been too low to permit infiltration of Mg-rich fluids. Alternatively, the Mg-bearlng fluids may have become depleted in magnesium during the course of dolomitization allowing preservation of some original calcite cement. In some cases, carbonate appears to replace quartz grains along their margins. The quartz grains are corroded and embayed at their 26 Plate 3: Carbonate grain with calcite core and dolomite rim in Type 1 sandstone (crossed nichols, 250x). 27 contacts with the replacing carbonate. Dolomite rhombs sometimes penetrate quartz grains, suggesting replacement rather than a solution-precipitation event. Alternatively, quartz overgrowths may have included the dolomite rhombs. Carbonate also occupies isolated, oversized pores in many of these sandstones, as well as pores approximating the average grain size of the sample involved. In these cases, precipitation of carbonate in pre-existing moldic or intergranular pores, perhaps with additional replacement of surrounding grains, may be indicated. Carbonate "patches" on the order of 0.5mm in diameter occur within the lower Bluefield sands. These are typically ovoid in shape, resembling the cross-section of a small bivalve. The ovoid may be completely cemented by large calcite crystals, but the central portion is usually cemented by megaquartz (coarse-grained authigenlc quartz). hematite, and/or calcite wl th dolomite surrounding the ovoid and decreasing in abundance away from it. Organic matter is often intermixed with the surrounding dolomite. These features are interpreted as follows: an original articulated fossil preserved pore space within the fossil; later the original shell material was mobilized and/or recrystallzed and dolomltized; the central cavity was then cemented by calcite, quartz, and/or hematite (Plate 4). Carbonate also fills fractures. Unlike other carbonate found in Type 1 Bluefield sandstones, the fracture-fill carbonate is composed entirely of calcite. This indicates that a second carbonate cementation phase occurred after dolomitization. Pore space is sometimes present between fracture-fill cement and walls of the fracture, indicating that 28 Plate 4: Ovoid in lower Bluefield sandstone largely cemented by quartz (crossed nichols, 63x). 29 reactivation of the fracture occurred after cementation, that leaching of the cement occurred, or that spreading of the fractures occurred during the thin section process. Generally, the calcite shows no sign of corrosion, suggesting that the pore space associated with the fracturing is due to reactivation or is a thin-section artifact. Other fractures are devoid of cement because they were not originally cemented or any original cement was totally leached out. IRON MINERALS Iron oxide (hematite) is present in Type 1 sandstones as 1) a stain and disseminated fine particles, 2) a replacement of carbonate, 3) large euhedral crystals, and 4) fracture-fill. Iron oxide in Bluefield Formation occurs as a stain and disseminated fine particles in red sands which are intercalated, often finely, with green sands. The color difference reflects the oxidation state of the iron. Chlorite is partly responsible for the coloration of the green sandstones. The degree of staining and abundance of iron oxide varies widely, possibly due to permeability differences. Hematite mixed with matrix and strongly strained labile fragments often make differentiation of these components difficult or impossible. Small disseminated grains of hematite are present in association with the hematite stain. Calcite and dolomite were both subject to replacement by iron oxide, ranging from staining along cleavage traces to total replacement. The occurrence and degree of replacement often varies greatly over small distances, perhaps indicating an advanced stage of lithification at the time of hematitization. Scholle (1979) notes that hematitizatlon may 30 occur late in diagenesis. Small-scale permeability differences may have been the controlling factor in replacement. Hematite also occurs as subhedral to euhedral crystals up to 0.25mm in diameter. In a few samples of green Type 1 sandstones, pyrite also occurs as large euhedral crystals of approximately the same size and shape. A few of these crystals have a pyrite core and a hematite rim (Plate 5). Hematite is probably pseudomorphic after pyrite. The large size and euhedral shape of the pyrite crystals indicates diagenetic origin. Pyrite also occurs in other forms in Type 1 sandstones. Some of the fractures present in Type 1 Bluefield sandstones are cemented by hematite. Often surrounding the hematite-filled fractures are "halos" of hematite stain and cement caused by lateral migration from the fracture through pore space and along microfractures. Scholle (1979) points out that fracturing infers extensive lithification, so this hematite phase was emplaced in a relatively late stage of diagenesis and possibly after exposure. The source of the hematite is problematical. Hematite cementation is generally attributed to intrastratal solution of iron-bearing minerals (Blatt, Middleton, and Murrey, 1980; Walker, 1974, 1977). Iron-bearing minerals, such as pyroxenes and amphiboles, are lacking in both red and green Type 1 sandstones, although some magnetite may be present in the opaque accessory mineral fraction. The dearth of iron-bearing minerals in both red and green Type 1 sandstones suggests that they were not present at the time of deposition. Hence, the iron oxide probably originated from sources other than constituent iron-bearing minerals, possibly from iron-bearing fluids produced by 31 Plate 5 Euhedral hematite with pyrite core (crossed nichols, 250x) 32 solution of iron-bearing minerals in associated shales or by diagenesis of clay minerals in associated shales or within the sandstones themselves. Oxidation of pyrite may have contributed minor amounts of iron to the system. PRESSURE SOLUTION FEATURES When pressure from overburden or tectonism exceeds hydrostatic pore pressure, solution may occur. Two types of pressure solution features occur within Type 1 Bluefield sandstones; intergranular pressure solution and stylolites. Intergranular pressure solution involves mutual dissolution and interpenetration between individual grains; the solution surface generally does not extend into adjacent grains. Stylolites are much larger-scale features in which a solution surface extends across many grains. Intergranular pressure solution tends to occur prior to extensive lithification when stresses are concentrated at grain-to-grain contacts. After extensive lithification, stresses are more evenly distributed throughout the rock and dissolution, if it occurs, will tend to proceed along the larger scale more continuous stylolitic surfaces (Heald, 1956). However, stylolites have been known to occur prior to extensive llthification (Heald, 1959). In samples that are relatively free of ductile material, such as rock fragments and matrix, and where carbonate cementation did not occur, intergranular pressure solution between quartz grains essentially occluded porosity. Where pressure solution occurred, quartz-to-quartz contacts are generally straight or curved, and a few are sutured. Such grain-to-grain contacts are characteristic of pressure solution (Heald, 33 1956). Sprunt and Nur (1977), in experimental studies on pressure solution, found that porosity loss (degree of pressure solution) increases with increased surface area; hence, finer grains are more susceptible to pressure solution. The fine grain size of Type 1 sandstones would have made them susceptible to pressure solution. Epitaxial quartz overgrowths, identified by thin "dust rims" present between the detrital core of the grain and its overgrowth, can be observed on some grains in samples that have undergone pressure solution. Straight, smooth and sutured contacts are characteristic of, but, not diagnostic of pressure solution; they may also be caused by simple epitaxial quartz cementation unrelated to pressure solution (Sibley and Blatt, 1976; Slppel, 1968). Therefore, quartz cementation unrelated to pressure solution may have been in part responsible for porosity occlusion in these areas. Stylolltes or solution features which are not restricted to contacts between individual grains are common in Type 1 Bluefield sandstones. Most stylolltes reported in the literature are relatively large scale features that, according to Wanless (1979), "have a cross-section resembling the trace of a stylus on a chart recorder", with "relief along stylolite surfaces anywhere from less than 1 mm to tens of centimeters". Stylolltes in Type 1 sands are of a smaller scale and lack the vertical relief referred to by Wanless. Stylolitic development occurs in Type 1 sands in two forms: 1) as "stylolitic seams" where solution has taken place along a distinct surface, and 2) as "solution seams" where solution has taken place not along a distinct surface but throughout a "broad vertical section" (Plate 6). 34 Plate 6: "Stylolltíc seam" and "solution seam" in Type 1 sandstone (crossed nichols, 25x). 35 "Stylolitic seams" are identified by concentrations of insoluble materials such as clay, heavy minerals and/or organic material along the solution surface (Heald, 1955). "Stylolitic seams" in Type 1 sands are generally marked by clay and organic matter. These seams often bifurcate into "swarms" of smaller seams similar to the anastomosing swarms described by Wanless (1979). "Stylolitic seams" occur most commonly in matrix-rich samples and at the contacts between matrix-rich and matrix-poor intervals within samples. The concentration of the "stylolitic seams" in these intervals is due to differences in resistance to compressive stress between matrix-rich and matrix-poor intervals (i.e., solution will tend to occur in Intervals less resistant to stress). The matrix-rich intervals are less resistant than the carbonate or quartz cemented matrix-poor intervals. These seams have frequently been stained by hematite which suggests that "stylolitic seams" may have served as conduits for migrating fluids during diagenesis. Also, some fractures are lined with residues of insoluble materials. Apparently, fracturing occurred preferentially along stylolites. As with "stylolitic seams", insoluble materials are concentrated within "solution seams". These seams sometimes display vertical offsets which were apparently caused by differential movement resulting from continued compressional stress after or during solution. The vertical offsets frequently have hematite seams parallel to their lengths (perpendicular to bedding and parallel to overburden stress direction). Small scale dislocations must have developed allowing infiltration of the hematite 36 AUTHIGENIC CLAY MINERALS Authigenic clays are clearly indicated in only one sample where kaolinite, perhaps mixed with minor amounts of silica and/or chlorite, cements part of a fracture. Elsewhere, growth of authigenic clays probably occurred but, because of the combined effects of compactional deformation, hematite staining and the presence of detrital clays, identification of authigenic clays is impossible in Type 1 sandstones. 37 TYPE 2 SANDSTONES CLASSIFICATION Individual samples of Type 2 sandstones are plotted on a ternary QFR diagram (Figure 7). Data for this diagram are listed in Appendix B. Twenty-four samples plot as quartzarenites, two as quartz wackes, 11 as sublitharenltes, and two as sublithic wackes. The two quartz wackes may be so classified because hematite was so thoroughly intermixed with other matrix material that it calculated as matrix. All sublitharenltes are from the mid portion of the Bluefield (outcrops 4 of the Bertha Sandstone, 6 of the Bradshaw Sandstone, 8 of the Indian Mills Sandstone, and 9 of the Droop Sandstone). Feldspar percentages are much higher in outcrops 8 and 9 than in other Type 2 sandstones. Outcrops 4, 5 and 6 are composed of both Type 1 and Type 2 sandstone interbeds. Samples of Type 2 sandstone from these outcrops are also plotted on Figure 7. Figure 6 plots the average of each outcrop. Three outcrops (2b of the Graham Sandstone, and 10 and 11 of the Droop Sandstone) plot as quartzarenites, whereas 5 outcrops (4 and 5 of the Bertha Sandstone, 6 of the Bradshaw Sandstone, 8 of the Indian Mills Sandstone, and 9 of the Droop Sandstone) plot as sublitharenltes. The grand mean for Type 2 sandstones plots at the quartz-rich end of the sublitharenite region. GRAIN SIZE Grain size in Type 2 Bluefield sandstones ranges from 0.083mm to 0.281mm. Within individual samples, grain size is relatively uniform. The mean for the Droop Sandstone (outcrops 9, 10, and 11) is 0.181mm. 38 Quartz Fragments Figure 7: Classification of Type 2 Bluefield sandstones. Arenites (less than 10% matrix) are symbolized as dots. Wackes (greater than 10% matrix) are shown with an "x". Circles indicate multiple samples. 39 The mean for the Graham sandstone at Buck (outcrop 2b) is 0.255mm, marking the coarsest-grained detrital sediment found within the Bluefield during this study. The mean for the Indian Mills Sandstone at Rock Camp (outcrop 8) is 0.118mm. Grain size for Type 2 interbeds within outcrops composed of both Type 1 and Type 2 sand interbeds are; 0.103mm in outcrop 4 , 0.176mm in outcrop 5, and 0.092mm in outcrop 6; but they contain rocks ranging from coarse silt to fine sand. Quartz overgrowths and/or pressure solution obscures original detrital grain size in most samples. PETROGRAPHY Quartz Quartz, the most abundant detrital constituent in Type 2 Bluefield sands, ranges in abundnce from 54.3% to 95.7% and averages 83.8%. Quartz overgrowths and/or pressure solution usually obscure original detrital grain shape. Where grain coats or dust rims outline the detrital grain, grains are rounded to very well rounded and moderately to highly spherical. Extinction is typically straight to slightly undulóse. Monocrystalline grains predominate, but polycrystalline grains and grains with strongly undulóse extinction are present. The quartz is clear but vacuoles are common. Inclusions, such as rutile, are rare. Some grains have subparallel lines of vacuoles known as Boehm lamellae. It is unclear if such lamellae in the Bluefield sands are caused by stress in the diagenetic environment or are inherited from an earlier depositional cycle. 40 Rock Fragments Rock fragments compose from 0.0% to 15.7% and average 6.4% of Type 2 sandstones. Metamorphic rock fragments (MRFs) include phyllite, schist and quartzite fragments. Shale and chert fragments compose the sedimentary rock fragments (SRFs). MRFs constitute from 0.0% to 14.7% and average 4.0% of Type 2 sandstones. Phyllitic and schistose grains, the predominant MRFs, are typically well rounded and slightly elongate in the B-axis direction of their constituent micas. Muscovite and lesser amounts of biotite compose the bulk of these micas. Rarer quartzose MRFs are well-rounded and spherical and consist of either stretched or equant subgrains. SRFs range from 0.0% to 6.0% and average 1.7% of Type 2 sandstones. Clay-shale and chert fragments are present in approximately equal amounts. Clay-shale fragments, which lack orientation of their constituent clays, are usually well-rounded, except where they have undergone extensive deformation. Some larger fragments are elongate and angular, reflecting short transport distances and suggesting intrabasinal origin. Well-rounded, highly spherical chert grains are present in small amounts. Feldspars Feldspars, although a minor constituent, occur in all but two outcrops (10 and 11 of the Droop Sandstone) of Type 2 sandstones. They range in abundance from 0.0% to 2.0% and average 0.3%. In outcrops 8 and 9 (Indian Mills and Droop Sandstone, 41 respectively) the feldspar, which averages 0.6%, appears to be a plagioclase, although It is untwinned and staining attempts were unsuccessful. Where unaltered, feldspar grains are equant and somewhat angular and exhibit cleavage. They are clear except along cleavage planes which are dark due to alteration. Typically, grains are partially dissolved. Dissolution appears to have started along cleavage traces and progressed inward, dividing grains into equant to elongate subgrains. The degree of this dissolution is variable within any given sample. While some grains are unaffected, moldlc porosity is caused by total dissolution of other grains. The majority of the porosity in outcrops 8 and 9 originates in this way. Moldic porosity in outcrops 10 and 11 may be due to complete dissolution of a similar grain type. Twinned plagioclase is present in trace to minor amounts in Type 2 interbeds in outcrops 4, 5 (Bertha Sandstone) and 6 (Bradshaw Sandstone), as well as in the more argillaceous samples of outcrop 8 (Indian Mills Sandstone). Trace amounts of feldspars occur in the carbonate-cemented basal part of outcrop 2b (Graham Sandstone). These feldspars have been extensively replaced by the carbonate, making accurate identification of the type of feldspar impossible. Carbonate Carbonate occurs in only one Type 2 sandstone. It occurs abundantly in the lower part of outcrop 2b (Graham Sandstone) where it constitutes as much as 44.7% of one sample. In outcrop 2b, carbonate averages 8.8%. The carbonate is poiklolitic, iron-stained and heavily twinned. As in Type 1 sandstones, dolomite, as well as calcite, is 42 present; and, similarly, it is probably secondary after calcite. Rock fragments, micas, and to a lesser extent quartz have been extensively replaced by the carbonate. Accessory Minerals Accessory minerals include detrital muscovite, biotite, zircon, tourmaline, rutile and opaques, as well as authigenic hematite and/or llmonite and clays. Together they range in abundance from a trace to 1.5% and average 0.4%. Muscovite, the most abundant accessory mineral, is ubiquitous in Type 2 sandstones in minor to trace amounts. It occurs as discrete flakes of variable size which are sometimes bent or kinked due to compressional deformation. Biotite is present in trace amounts in a few Type 2 sandstones. Zircon is also ubiquitous in trace to minor amounts and is by far the most abundant heavy mineral. Most grains are well-rounded, but a few are subhedral to euhedral. Large, well-rounded, highly spherical opaques are present in trace amounts. A few very well-rounded, highly spherical, pleochrolc tourmaline grains were found. Opaques, zircon, and other accessory minerals are concentrated along stylolites. Iron oxide is present as pore-filling cement, fracture-fill, stain on grain coatings, and disseminated granular material. Trace amounts of authigenic clay form booklets and flakes lining and filling pores, and lining graln-to-grain contacts. Clay flakes are typically oriented randomly or parallel to grain surfaces, but, rarely are oriented normal to these surfaces. Clays are sometimes stained by iron oxide. 43 Matrix Matrix material ranges from a trace to 17.3% and averages 4.7%. Matrix includes fine-grained phyllosilicate material, clay minerals, very fine-grained mineral particles, and iron oxide. Clays and iron oxide are included because they are often intermixed and cannot be differentiated. Hence, matrix includes grain coats and pore-filling clay and iron oxide. 44 DIAGENESIS OF TYPE 2 SANDSTONES Dtagenetic alteration of Type 2 (coarse-grained, clean) sandstones includes porosity reduction due to mechanical compaction, quartz cementation, intergranular pressure solution, and minor amounts of calclte cementation and growth of authigenic clays. Other diagenetic processes include stylolitization, fracturing, and precipitation of iron oxides. Most porosity in these sands is primary, but some secondary porosity was produced by dissolution of feldspars and by fracturing. MECHANICAL COMPACTION Mechanical compaction is evidenced by deformation of labile fragments (MRFs, SRFs, and micas). MRFs and micas are typically bent or kinked at one or more points. This deformation squeezes parts of the grains into surrounding pore space, contributing in a minor way to llthlfication by cementing adjacent grains together. Occasionally, localized compression of micas caused separation along cleavage planes. Pore space between cleavage planes was later filled by quartz cement. Clays of SRFs lack orientation and show no evidence of internal deformation as do the MRFs. Rather, portions of the relatively soft SRFs are "injected" into the interstices between more rigid surrounding grains (i.e., quartz). The degree of deformation of labile fragments, particularly MRFs, varies widely both between samples and within samples. Some variation is attributable to the type or orientation of the fragment involved. MRFs with finer-grained micas underwent more deformation than those with 45 coarser-grained micas. Deformation also varies widely between compositionally similar MRFs, because of variation in their orientation in the timing of cementation. Early cemented intervals undergo less mechanical compaction and preserve the Integrity of the labile fragments. Uncemented intervals undergo more mechanical compaction causing more deformation of the labile grains. POROSITY Type 2 sandstones are not highly porous, yet both primary and secondary porosity are present. All Type 2 sandstones contain some porosity, with the exception of outcrop 2b (Graham Sandstone) in which porosity is totally occluded. Primary intergranular porosity occurs only in clean, coarse-grained samples. There are minor amounts in all outcrops of the Droop Sandstone and in outcrop 8 (Indian Mills Sandstone). Intergranular pores are highly angular, often three-sided, and result from incomplete pore closure by quartz overgrowths (Plate 7). No evidence was found for a precursor cement. Hence, intergranular porosity in these sections is considered to be reduced primary porosity. With the exception of outcrop 2b, moldic porosity occurs in all Type 2 sandstones, but it is most common in the clean, coarse-grained samples. It is particularly abundant in the Droop Sandstone and in outcrop 8 (Indian Mills Sandstone). In outcrops 10 and 11 (Droop Sandstone), moldic pores are void and offer no evidence of the dissolved grain. In outcrops 8 and 9 (Indian Mills and Droop Sandstones) a single grain type (untwinned plagioclase) has undergone dissolution and is 46 Plate 7 Primary intergranular porosity in Type 2 sandstone (crossed nichols, 250x). 47 responsible for moldic porosity. Dissolution proceeded from grain margins and cleavage traces. Undissolved portions of these plagioclase grains remain clear and unaltered. The same grain type may have been responsible for moldic porosity in outcrops 10 and 11 (Plate 8). Porosity associated with fracturing is present in a few Type 2 sandstones. Fracturing occurred only in relatively Impure, fine-grained samples, but it is abundant where present. Overall, fracture porosity constitutes a minor proportion of the porosity in Type 2 sands. Most fractures contain no cement, and lack of remnant patches of cement within them suggests they were never cemented and probably formed late in the dlagenetic history of these rocks. One fractured sample contains quartz cement. CARBONATE Carbonate occurs in only one Type 2 sandstone (the basal part of outcrop 2b, Graham Sandstone). The carbonate is composed of both calclte and dolomite. It is poikllotopic, iron-stained, and heavily twinned; and it replaces, in part or completely, all observed grain types. It was particularly effective in replacing rock fragments, micas, and feldspars, which frequently appear as "skeletal" grains in which the original nature of the grain is barely preserved (Plate 9). While feldspars occur in the carbonate-cemented basal part of outcrop 2b, its upper part contains no feldspar. Although the feldspars are extensively replaced, the carbonate cement in the base of the outcrop prevented feldspar dissolution during quartz diagenesis. This suggests that carbonate cementation was early (l.e., the carbonate cement 48 Plate 8 Moldíc porosity formed through partial dissolution of feldspar in Type 2 sandstone (crossed nichols, 250x). 49 Plate 9 Carbonate replacement of feldspar (crossed nichols 160x) 50 prevented dissolution of the feldspars which apparently occurred in the upper part of the outcrop). Quartz also underwent replacement by the carbonate. Replacement proceeded from the margins of the grains, as evidenced by irregular grain boundries where carbonate-filled embayments penetrate quartz (Plate 10). The quartz grains are also replaced along internal linear zones of weakness, perhaps along pre-existing vacuole trains. Replacement of quartz was extensive in some cases. Quartz "shards", apparently remnants of an extensively replaced quartz grain, are found floating in the carbonate. Alternatively, such cases may represent the remnants of an originally quartz-rich rock fragment where carbonate selectively replaced other constituents. Most quartz grains are surrounded by "halos" of unstained, untwlnned carbonate (Plate 10). Where quartz grains have been partially replaced internally by carbonate, that carbonate is also untwlnned and unstained. At least two possibilities exist for the formation of these "halos": 1) a two-stage replacement of quartz by carbonate in which a second phase of replacement produced the "halos" after twinning and staining of the early carbonate; 2) grain rotation accompanied by recrystallization of carbonate adjacent to quartz grains. HEMATITE Hematite occurs in Type 2 sandstones as a stain, as finely disseminated grains, and as pore-filling cement. Hematite stains clay minerals and to a lesser extent micaceous rock fragments. All three types of hematite occur together, suggesting only one phase of 51 Plate 10: Carbonate-cemented Type 2 sand. Note marginal replacement of quartz by carbonate; clear carbonate"halo" around quartz grain in lower left of photo and; partial replacement of feldspar in lower right of photo (crossed nichols, 63x). 52 hematitizatlon. Hematite fills both primary and secondary porosity. Secondary porosity in Type 2 sands shows no evidence of reduction and, therefore, probably occurred relatively late in diagenesis. Early formed secondary porosity would have been at least partly occluded by mechanical compaction or quartz cementation. Because hematite infills secondary porosity, hematitizatlon must have occurred late in diagenesis, possibly at outcrop. CLAY MINERALS Clay minerals in Type 2 Bluefleld sands occur as discrete flakes and coatings around quartz grains, as inclusions within authigenic quartz, and rarely as pore-filling material. The clay is composed largely of illite but may contain some kaolinite. Clays are sometimes stained by iron oxide, making accurate optical identification difficult or impossible. Clay minerals in Type 2 sandstones may be both detrital and authigenic. Authigenic clays are generally distinguished from detrital clays by their distinctive morphologies. However, the combined effects of mechanical compaction, quartz cementation and pressure solution can make distinction between authigenic or detrital origins impossible. In a few cases, it is possible to identify the origin of the clay. For instance, clay grain coatings between the detrital cores of quartz grains probably developed prior to deposition. Clays are sometimes clearly authigenic, as where kaolinite booklets are found filling pores and where clays are oriented perpendicular to quartz grain boundaries (Plate 11). But, the precise origin of clays could not be routinely determined 53 Plate 11: Authigenlc clay surrounding quartz grain and between quartz grain and its overgrowth (crossed nlchols, 160x). 54 QUARTZ AUTHIGENESIS The most important processes in porosity reduction and lithificatlon of Type 2 Bluefield sandstones were quartz cementation resulting from pressure solution and "quartz enlargement" (quartz cementation unrelated to pressure solution). Together, these two processes significantly reduced and sometimes occluded primary porosity (Plate 12). Both "quartz enlargement" and intergranular pressure solution are relatively early diagenetic events. "Quartz enlargement" requires pore space into which overgrowths can expand and so must precede extensive lithification. Lithification also hinders pressure solution by distributing stresses more evenly throughout the rock, rather than at the grain-to-grain contacts where intergranular pressure solution occurs (Heald, 1956). An important factor in controlling which of these two processes occur is the presence and thickness of clay coatings on detrltal quartz grains (Plate 13). Clay coatings inhibit the formation of quartz overgrowths by blocking nucléation sites on the surfaces of quartz grains (Heald and Larese, 1974). Grain coatings of sufficient thickness (thick enough to prevent diffusion across the coating?) will prevent "quartz enlargement" and preserve primary porosity. Where such coatings are lacking or Incomplete, nucléation sites are available and quartz overgrowths will form, provided that silica is available and that conditions are otherwise favorable for quartz growth (Heald and Larese, 1974). Where clay coatings are absent, overgrowths totally surround 55 Plate 12: "Quartz enlargement" vs pressure solution in Type 2 sandstone. Area in top of photo dominated by "quartz enlargrment. Bottom part of photo shows pressure solution (crossed nichols, 25x). 56 Plate 13; Grain coatings, incomplete overgrowths and moldic porosity in Type 2 sandstone (plain light, 25x). 57 detrítal grains and most grain-to-grain contacts are between overgrowths. Where grain coatings are incomplete, "irregular overgrowths" are formed (Heald, and Larese, 1974) because localization of nucléation sites causes restriction of the overgrowths. A given detrital grain may possess a well developed overgrowth along part of the grain, but the overgrowth may be absent along other parts of the grain (Plate 14). Detrital grain-to-overgrowth contacts become common (i.e., overgrowths from one grain often are in contact with detrital cores of adjacent grains on which clay coatings prevented overgrowth formation). Where grain coatings are thin or absent, epitaxial quartz overgrowth formation ("quartz enlargement") was the dominant process by which Type 2 sandstones were cemented. Epitaxial overgrowths are identified by "dust rims" between detrital cores and the overgrowths, or by variations in other characteristics between the detrital cores and their overgrowths. For example, overgrowths typically contain fewer inclusions (except for clays) than the detrital cores, which contain vacuole trains and other linear features that terminate against overgrowths. Overgrowths in Type 2 sands are largely "irregular overgrowths". Contacts between clay-coated detrital cores and overgrowths of adjacent grains are common in these intervals. These contacts are fairly weak and sands cemented in this manner are often friable (Heald and Larese, 1974). The friable nature of the Droop Sandstone is likely due to cementation in this fashion. While "quartz enlargement" was the dominant cementation process in intervals where grain coatings are thin, evidence of pressure solution is rarely lacking. Most grain-to-grain contacts are smooth or straight. 58 Plate 14: Incomplete quartz overgrowth (crossed nichols 63x) 59 but the interpenetration of detrital cores, marked by sutured contacts, suggests that some pressure solution occurred. Cementation by overgrowths was apparently incomplete when overburden (?) pressure Initiated pressure solution. In Intervals with thin grain coatings, pressure solution was relatively minor and contributed little cement to the system. Where grain coatings are complete and of sufficient thickness, quartz enlargement is Inhibited and primary porosity is often preserved. When overburden or tectonic stress becomes great enough, solution may occur. Pressure solution involves solution at graln-to-grain contacts. Dissolved silica migrates along grain boundaries and is precipitated in areas of lower stress (l.e., within adjacent pore space). When pressure solution occurs in sands that lack grain coatings (clean sands), a water layer adsorbed at the margin of the grain is the only migration path available to dissolved silica. Clay coatings tend to enhance pressure solution by providing a wider diffusion path for the silica. The silica migrates either between the clay coating and the detrital grain or between the clay layers (Weyl, 1959). During the latter process, clay may become incorporated within the authigenic quartz as inclusions. Sometimes such inclusions are oriented parallel to prism planes within the authigenic quartz, creating a feature termed "polygonal-grid" quartz (Heald and Larese, 1974). In intervals where clay coatings are relatively thick. Intergranular pressure solution was the dominant lithification process. Compared to Intervals cemented mostly by "quartz enlargement", pressure solution intervals contain more detrital core-to-detrital core contacts. 60 more sutured contacts, and fewer and smaller overgrowths identifiable by dust rims. Solution is most easily Identified at detrital core-to-detrital core contacts, but it also probably occurred between overgrowths and detrital cores, and between adjacent overgrowths. Grain coatings in Type 2 sandstones may cover both a detrital grain and its overgrowth, indicating that silica diffused mainly between the clay coating and detrital grain. As quartz precipitated on the detrital grain, the clay coating "migrated" away from it, leaving the overgrowth between the detrital grain and the clay coating. More commonly, clay flakes are included within the authigenic quartz. Most clay inclusions within authigenic quartz in Type 2 Bluefield sands are oriented randomly. "Polygonal-grid" quartz is present but not common. Most of the authigenic quartz formed by pressure solution in Type 2 Bluefield sandstones formed epitaxially. Some authigenic quartz is not in optical continuity with any observed grain, but this authigenic quartz may be epitaxial on grains outside the plane of the thin section. Grain size tends to be smaller in zones with extensive pressure solution than in zones cemented by "quartz enlargement". These zones are small in scale and may vary within a single thin section. Early formed overgrowths tend to increase grain size, while pressure solution has less effect on grain size; and so grain size difference may reflect authigenesis. Alternatively, the grain size difference may be depositional in nature. Sprunt and Nur (1977) found that degree of pressure solution increases with decreased grain size, and so intervals of finer grain size would have been more susceptible to pressure solution. A combination of these two factors may be responsible for the 61 observed correlation between grain size and method of lithification. Clay coatings of sufficient thickness will inhibit pressure solution by cushioning the effects of overburden pressure and reducing stress at graln-to-grain contacts. The thickness at which clay coatings cease promoting and begin inhibiting pressure solution has not been documented (Sibley, 1975; Sibley and Blatt, 1976). In a few samples of Type 2 sandstones grain coatings were apparently of sufficient thickness to prevent pressure solution. Summary Type 2 Bluefield sandstones were cemented by both "quartz enlargement" and intergranular pressure solution. Most Intervals show the effects of both processes, and all gradations between cementation totally by "quartz enlargement" and totally by pressure solution can be observed. Clay coatings (largely illite) on detrital grains are almost ubiquitous in Type 2 sands, but they vary in thickness. The thickness of clay coatings correlates with changes in dlagenetic processes within the sands. "Quartz enlargement" began before pressure solution where nucléation sites were available for quartz growth. In intervals with relatively thick and complete clay coatings "quartz enlargement" was inhibited. Increased overburden stress later in diagenesis initiated solution at grain-to-graln contacts (intergranular pressure solution). Pressure solution, aided by the presence of clay coatings, produced additional free silica for quartz authlgenesis, which completed 62 cementation of Type 2 sandstones. STYLOLITES AND FRACTURES Stylolites occur in only a few of the Type 2 sandstones sampled. They are characterized by concentrations of insoluble materials such as clay minerals, heavy minerals, and organic matter along the stylolitic surface. Most stylolites occur in the more argillaceous samples of Type 2 sandstone, and most are oriented parallel to bedding. They were probably caused by overburden pressure. Fracturing later, occurred preferentially along these stylolites. One sample, taken from the base of outcrop 9 (Droop Sandstone), contains stylolites which are oriented normal to bedding. These were caused by directed stress, possibly associated with folding and thrust faulting in the region, in the horizontal plane. Quartz overgrowth formation and stylolitization tend to occur in mutually exclusive samples of Type 2 sandstones, stylolites in argillaceous samples and quartz overgrowths in "cleaner" samples. Therefore, no cross-cutting relationships were observed and relative timing of these two events could not be determined. All fractures observed in Type 2 sandstones are oriented parallel to bedding, and were probably caused by release of overburden pressure. Fractures which occurred along pre-existing stylolite surfaces may have been opened during the thin section process. Most of the fractures contain no cement and were probably never cemented. This suggests that fracturing occurred late in the dlagenetic history of these rocks. One fracture set was cemented by quartz This indicates that 63 either a second generation of quartz authigenesis followed quartz cementation, or free quartz which remained in the system after primary porosity reduction cemented this fracture. 64 DIAGENETIC SEQUENCE Dlagenesis within Bluefield sandstones can be separated into early, middle and late stages. The sequence discussed below refers to both Type 1 and Type 2 sandstones except where noted. Diagenetic events are summarized in Figure 8. EARLY STAGE OF DIAGENESIS Early diagenetic events include mechanical compaction and formation of authigenic pyrite, clay minerals (largely illite), calcite, and hematite. The first minerals to form were pyrite and calcite. Calcite probably formed from carbonate present at or near the sediment-water interface. Some early formed calcite was subsequently dolomltized. Detrital quartz grains and other grain types were partially replaced by calcite. Evidence from the base of outcrop 2b (Graham Sandstone), where calcite authigenesis prevented dissolution of feldspars, suggests that this replacement occurred early. Oxidation of some of the pyrite to hematite occurred and, probably concurrently, some calcite and dolomite were also partly replaced by hematite. Authigenic illite formed grain coatings (of variable completeness and thickness) on quartz grains in Type 2 sandstones. Some of these grain coatings may be predeposltional. The fact that they were "involved or mobilized" during quartz authigenesis, a process which occurred in the middle stage, suggests that they formed early. Illite probably formed in Type 1 sandstones as well. This illite, as well as other authigenic clay minerals, is mixed with detrital clays. DIAGENETIC DIAGENETIC STAGE EVENT early middle late HEMATITE ?? ?? AUTHIGENESIS CLAY MINERAL ?? — AUTHIGENESIS CALCITE “ ?? AUTHIGENESIS DOLOMITIZATION MECHANICAL ? ? ? COMPACTION QUARTZ — AUTHIÇENESIS INTERGRANULAR PRESSURE SOLUTION FRACTURING STYLOLITIZATION 1 1 1 1 PYRITE AUTHIGENESIS Figure 8. Sequence of dlagenetic events 66 Mechanical compaction, especially through deformation of labile fragments, begins only after shallow burial (Blatt and others, 1980). Compaction began early and continued throughout the early stage of diagenesis. MIDDLE STAGE OF DIAGENESIS The middle stage of diagenesis is characterized by formation of quartz overgrowths and stylolites, and by Intergranular pressure solution. Free silica began to precipitate as epitaxial overgrowths on quartz grains, a process particularly important in Type 2 sandstones. Mechanical compaction during the early stage of diagenesis in Type 1 sandstones prevented significant quartz authigenesls by occluding primary porosity. Later, as overburden pressure increased, intergranular pressure solution began. This process, aided by the presence of clay coatings on detrital grains, released additional silica which precipitated as epitaxial overgrowths and randomly oriented pore-filling cement. Stylolitization may occur prior to. during, or after quartz cementation within sandstones. In fact. it may be an important contributor of silica when it occurs before or during cementation (Heald, 1959). Stylolites occur most frequently in the more fine-grained and argillaceous components of the Bluefield sandstones, which contain only minor amounts of authigenlc quartz. Therefore, cross-cutting relationships could not be observed. Stylolitization is placed in the middle stage of diagenesis based on its relationship with fractures. Fracturing occurred preferentially along stylolites during 67 the late stage of diagenesis. Stylolitization clearly preceded fracturing and is considered to be a middle stage event. LATE STAGE OF DIAGENESIS The late stage of diagenesis includes events which occurred after extensive lithification of Bluefield sandstones. Important events include fracturing; the infilling of many fractures by authigenic quartz, calcite, hematite and clay minerals; and the formation of moldic porosity by dissolution of feldspars. Fracturing typically occurs after extensive lithification, when repacking at the graln-to-grain level can no longer close the fractures. Stylolites served as preferred sites for fracturing, suggesting that fracturing occurred relatively late in the diagenetic sequence. Bluefield sandstones were fractured both parallel and at high angles to bedding. Fractures at high angles to bedding were probably formed at depth by overburden pressure, and may have occurred in either the middle or late stage of diagenesis. Fractures parallel to bedding probably occurred late in response to release of overburden pressure. Many of these fractures were later cemented by calcite, hematite, quartz, or clay minerals. Only one of these mineral phases is usually present in any given fracture, and so relative timing of these events could not be determined. One fracture contains both calcite and clay minerals. The calcite appears somewhat corroded, which possibly indicates that calcite authigenesls preceded clay mineral authigenesis. Variation in pore fluid chemistry may have been responsible for variations in cement type. Feldspar dissolution produced secondary moldic porosity during this 68 diagenetíc stage, particularly in Type 2 sandstones. Moldic pores contain no quartz cement. Had this porosity been produced before or during quartz authigenesis, the pores would have been at least partly Infilled by quartz cement. Feldspar dissolution must, therefore, have occurred after quartz authigenesis (i.e., in the late stage of diagenesis). Occasionally pores are partially cemented by hematite, but otherwise they contain no late stage cement, suggesting that late-stage quartz, calclte and clay mineral authigenesis preceded feldspar dissolution and, possibly, hematite authigenesis. Hematite authigenesis either postdated or co-occurred with feldspar dissolution. SUMMARY The most important diagenetic events in Bluefield sandstones were mechanical compaction and quartz cementation. During the early stage of diagenesis, mechanical compaction was the dominant diagenetic process in the Type 1 sandstones which contain large percentages of ductile grains. At the end of the early stage of diagenesis, lithification was essentially complete and primary porosity essentially occluded in Type 1 sandstones. At the beginning of the middle stage of diagenesis, significant primary porosity remained in Type 2 sandstones. Large amounts of silica available to the system initiated formation of quartz overgrowths. Continued burial during the middle stage of diagenesis induced intergranular pressure solution. This released additional silica, further promoting quartz authigenesis and completing lithification of Type 2 sands. Late stage diagenetic events include minor secondary porosity formed through fracturing. feldspar 69 dissolution, and partial infilling of secondary porosity by various authigenic minerals. 70 DEPOSITIONAL SETTING GENERAL During the late Mlsslssipplan the study area was located approximately 5 to 10 degrees south of the paleoequator (Humphrevllle, 1981; Scotese and others, 1979; Bambach and others, 1980; deWitt and McGrew, 1979). Figure 9 is a map adapted from deWitt and McGrew (1979) showing generalized Chesterian paleogeography. To the east, Appalachia was developing as an Andean-type mountain chain (Scotese and others, 1979). Uplift to the east caused large volumes of detritus to be deposited in the area (Bambach and others, 1979; deWitt and McGrew, 1979). These sediments were deposited in a shallow, slowly subsiding basin which occupied southeastern West Virginia during this time (Scotese and others, 1979). PROVENANCE Metamorphic rock fragments (MRFs), such as slate and phyllite fragments, are very abundant in Bluefield sandstones. Slate, phyllite and chlorite-bearing MRFs suggests erosion of a low-grade metamorphic source. Higher metamorphic grade fragments, such as biotite and coarser-grained (schistose) fragments, are also present. This suggests that source rocks were composed of multiple metamorphic facies or that multiple sources contributed sediments to the area. Minor quantities of sedimentary rock fragments are present. These are primarily claystone clasts and a few siltstone clasts. Although they may represent erosion of a sedimentary source, they are most likely 71 Figure 9 : Upper Mississippian (Chesterian) paleogeography (after Craig and Varnes, 1979). Shaded area represents marine conditions. Darkened area indicates study area. 72 Intrabasinal. No rock fragments clearly indicative of a plutonic source were found. PREVIOUS INTERPRETATIONS Whisonant and Scolaro (1980) interpreted a stratigraphic section from the middle part of the Bluefield Formation in Mercer County, West Virginia as a nearshore deposit. Inferred environments included shallow subtidal, lower intertidal, middle intertidal, and higher intertidal. The section was found to be regressive in nature. Humphreville (1981) investigated the stratigraphy and paleoecology of the Bluefield Formation in Mercer County, West Virginia and Tazewell County, Virginia. The lower Bluefield, composed primarily of argillaceous wackestones, was interpreted to represent deposition during the waning periods of storm events. The upper Bluefield, composed of olive-green and maroon mudstones lacking both marine and terrestrial fossils, was interpreted to represent deposition as a prograding muddy shoreline or in a muddy marsh setting. Humphreville interpreted the Indian Mills Sandstone, a coarse quartzose sandstone between the upper and lower Bluefield, as a crevasse splay and stated that it is the only one of Reger's (1926) members still recognized. Interbedded clays and coals are interpreted as terrestrial swamp deposits. In summary, he stated that the formation represents a shallow water, muddy environment with tidal flats, crevasse splay sands, and muddy shoreline and swamp deposits. Swires (1972) studied sediments of the Mauch Chunk Group in the Hurricane Ridge Syncline in Mercer, Monroe, and Summers Counties, West 73 Virginia. He interpreted the lower Bluefield as open marine deposits which grade upward into "deltaic/fluvial" and lagoonal sediments. He, like Humphreville (1981), recognized only the Indian Mills Sandstone as a member within the Bluefield. He Intrepreted the Indian Mills as a "deltaic/fluvial" deposit. McColloch (1957) studied the Bluefield Formation in Mercer, Monroe, Summers, and southern Greenbrier Counties, West Virginia. He noted that the basal Bluefield is predominantly marine limestone and shale with minor terrestrial sandstones and shales, and that the upper Bluefield is predominated by terrestrial shales and sandstones with minor marine and freshwater limestones. Unlike Swires and Humphreville, McColloch places the Droop Sandstone of Reger (1926) at the boundary between the lower and upper Bluefield. McColloch claimed that the limestones of the lower Bluefield can be traced throughout the study area, but that the marine limestones of the upper Bluefield, including the Raines Corner and Bertha Limestones of Reger (1926), lens out or undergo facies changes north of Pence Springs (sample site 12 of this report). He also noted that the Bluefield is thinnest at Pence Springs and thickens both to the north and south from there. He reported deltaic deposits to the north in his Clintonvllle section, while his southern sections (not specifically designated but certainly south of Pence Springs) were deposited in marine conditions. Otherwise, he referred to upper Bluefield deposition as "terrestrial". Manspeizer (1958) studied the Bluefield Formation in Greenbrier and Pocahontas Counties, West Virginia. He interpreted those units below the Droop Sandstone to be largely of marine origin (Lillydale, Glenray, 74 Reynolds, and Ada members of Reger), with minor lagoonal (Bickett Shale) and "transitional-littoral" deposits (Webster Springs Sandstone). Units above the Droop were interpreted variously as transitional-deltaic, littoral, and lagoonal deposits within an overall deltaic setting. The Droop was interpreted as a beach (littoral) sand. Manspeizer recognized a delta distributary north of Droop Mountain in Pocahontas County. He noted that the Droop Sandstone thickens toward the north, reaching its maximum thickness at Droop Mountain, north of which it undergoes facies changes. He stated that north-flowing currents piled up Droop sediments against the delta producing the increased thickness. 75 DEPOSITIONAL ENVIRONMENTS LOWER SANDSTONES Lower Bluefield sandstones include the Webster Springs and Edray as named by Reger (1926). These sands are most prominant north of the study area and attempts to trace them into the area are tenuous at best. Lower sandstones of this study are best thought of as sands which occur at horizons similar to those of the named sandstones to the north and not necessarily contiguous units. Three outcrops were sampled in the lower part of the Bluefield Formation. Two of the outcrops sampled (outcrops S and J) were first described by Reger (1926) who assigned them to the Webster Springs Sandstone. The third outcrop sampled (outcrop R) was located lower in the Bluefield and may be the equivalent of the Edray sandstone of Reger (1926). All three outcrops consisted of Type 1 sandstone. Outcrop S consists of calcareous, very fine-grained sand which shows no grain size sequence. It ranges from greenish-brown to buff, cross-bedded sand in its lower part to green, flaggy and ripple-marked sand in its upper part. Quartz percentage is low (mean = 61.7%). Rock fragment percentage is relatively high (mean = 21.2%). Outcrop J is composed of 3 units of Type 1 sandstone which are intercalated with yellow-brown calcareous shale. The coarse-grained units are variously brown, greenish-brown or gray and massive to ripple-marked. Grain size in the "coarse-grained" units ranges from coarse silt to very fine sand. The mean grain size falls in the coarse silt range. Quartz percentage is low (mean = 56.1%). Rock fragment 76 percentage is highly variable, ranging from a trace to 30.0% and averaging 10.6%. Carbonate percentage ranges from a trace to 48.3%. Stratigraphic evidence suggests that the Webster Springs Sandstone is encased in marine deposits. The Webster Springs Sandstone (outcrops S and J) is underlain by the marine Glenray Limestone. The overlying Bickett Shale contains a red zone, but also contains interbedded limestones, particularly in its upper portion where it grades upward into the marine Reynolds Limestone (Reger, 1926; McColloch, 1957). The Bickett is sandy at its base. This sequence suggests that a "pulse" of clastic sedimentation occurred in what was otherwise a basin dominated by carbonate deposition. This influx of elastics temporarily displaced carbonate deposition. Resumption of carbonate deposition is recorded by the transition of the top of the Bickett Shale into the overlying Reynolds Limestone. Moreover, while the Webster Springs is massive at outcrop S, it interfingers with apparent marine shales at outcrop J. This suggests that the Webster Springs was deposited under marine conditions. Similar sands, particularly in the Cretaceous of Texas and the Rocky Mountain region, have been interpreted as "shelf ridge sands" (Swift and Rice, 1984). These sands are formed by winnowing of sandy shales (muds) largely by storm induced currents (Swift and Rice, 1984). Ripple-marks, cross-bedding and horizontal bedding are the most common sedimentary structures in these sands (Swift and Rice, 1984). They are also the most common structures in the Webster Springs Sandstone. Most documented shelf sands are, however, more extensively cross-bedded and somewhat coarser-grained and better sorted than outcrops of the Webster 77 Springs observed in this study. Grain size is in part a function of the grain size of available sediment; i.e., grain size in the Webster Springs may include the coarsest materials that were available. Size and kind of bedform (especially cross-bedding) are a function of the energy of the depositional environment. The difference in bedforms, finer grain size, and poorer sorting suggests that basin energy, and more precisely the size and intensity of storms, was higher in the Cretaceous examples than in the Appalachian basin when the lower Bluefield was being deposited. The Webster Springs Sandstone probably developed through winnowing of the muds of the lower Bluefield shale and represents shelf sand ridge deposition. Most shelf sand ridges are linear features. Outcrop S is relatively thick, coarse-grained and massive and probably was deposited near the axis of a sand ridge. Outcrop J, which is interbedded with marine shales, probably represents deposition along the lateral margin of a ridge. Such intercalation of sands with shale or mud is common at the margins of shelf sand ridges (Swift and Rice, 1984). Outcrop R (Edray Sandstone?) is calcareous, ripple-marked and very fine-grained. Grain size ranges from coarse silt to very fine-grained sand and averages 0.046mm. Quartz percentage is low (mean = 65.6%). Rock fragment and matrix percentages are high (averages of 14.6% and 13.5%, respectively). Like outcrops J and S, outcrop R is surrounded by marine sediments. Processes that formed outcrop R were probably similar to those that formed outcrops J and S. Outcrop R, therefore, is interpreted as a shelf sand ridge. The fine grain size and lack of cross-bedding suggests that outcrop R was deposited at the distal margin 78 of a sand ridge. DROOP SANDSTONE The Droop Is a Type 2 sandstone. It is sheet-like in geometry, clean, and coarse-grained, and it lies at the transition between the upper and lower parts of the Bluefield Formation. Grain size within the Droop ranges from 0.09mm to 0.34mm and averages 0.19mm (fine sand). Grain size fines upward; however, quartz authigenesis obscures original detrital grain size and so this trend may not be significant. Quartz percentage is high (88.3%). Rock fragment and matrix percentages are low (combined mean = 7.2%). The Droop overlies fossillferous marine shales (Talcott Shale) and is overlain by a sequence of shales (Raines Corner and Possumtrot) which include coal horizons (Reger, 1926). The overlying shales are highly variable in ,appearance. They may be gray, blue-green, black or olive and occasionally red in color. They Include carbonaceous material as well as pyrite, siderite and carbonate nodules. Both plant and marine fossils have been reported. Sandstone Interbeds and lenses are also found (Reger, 1926; McColloch, 1957). These shales would appear to be estuarine and/or lagoonal deposits associated with marsh environments. The Droop appears to be a nearshore coastal sand. The upper part of the Droop is typically horizontally stratified or exhibits low angle cross-bedding, and it is sometimes ripple-marked. The upper contact is gradational. The lower part is extensively cross-bedded. Most of the cross-bedding is trough cross-bedding, but tabular planar cross-bedding is present at some exposures. A relatively 79 narrow zone, sometimes present just above the lower contact, is horizontally stratified or massive. The lower contact is erosional. The clean, well-sorted, coarse-grained, quartz-rich (orthoquartzitic) lithology of the Droop is characteristic of barrier island and strand plain deposits (Galloway and Hobday, 1983; Balazs and Klein, 1972). Strand plain and barrier island models, as summarized by McCubbin (1983), show a general beach to offshore trend consisting of 4 environments: 1) horizontally stratified beach deposits; 2) cross-bedded upper shoreface deposits; 3) horizontally stratified lower shoreface deposits and; 4) offshore deposits. The contact between the beach and upper shoreface is sharp. The contact between the upper shore-face and lower shoreface is gradational. The lower shoreface grades into and is interbedded with the off-shore environment (McCubbin, 1982; Galloway and Hobday, 1983). Beach and upper shoreface deposits are present in the middle and upper portions of the Droop. However, the lower contact of the Droop Sandstone is erosional and its basal portion is cross-bedded, unlike the horizontally stratified and gradational lower portion described in these models. Tidal inlet deposits, which are associated with barrier islands, have erosional lower contacts and are characterized by extensive high-angle cross-bedding (McCubbin, 1982; Galloway and Hobday, 1983). Lateral migration results in replacement of the normal beach to offshore sequence by cross-bedded tidal inlet sands. Continued migration allows reestablishment of beach and upper shoreface environments which then overlie the tidal inlet deposits. Large proportions of the barrier island may be comprised of tidal inlet deposits as a result of this 80 process. The vertical progradational sequence thus formed consists of a lower cross-bedded zone with a scoured base overlain by a horizontally stratified zone (Galloway and Hobday, 1983). This is very similar to the sequence observed in the Droop. The Droop was deposited as a barrier island complex and consists primarily of tidal inlet and beach deposits. The lower, cross-bedded zone represents tidal inlet deposition. The upper, horizontally stratified zone of the Droop represents beach (foreshore) deposition, but may also contain washover fan and/or flood tidal delta deposits. Cross—bedded upper shoreface environments would accompany re-establishment of the beach environment after tidal inlet migration (Galloway and Hobday, 1983). Therefore, upper shoreface deposits are probably present between in the middle part of the Droop. No dune deposits were identified. Dickenson and others (1972) noted that such deposits would likely be destroyed during reworking. In addition. the low offshore slope of the basin would have been conducive to barrier island formation provided a source of sand existed. The sheet-like geometry of the Droop is due to the progradation of the barrier island. UPPER SANDSTONES Introduction Clastic Mississlppian strata in southeast West Virginia are considered to be deltaic in origin (deWitt and McGrew, 1979; Craig and Varnes, 1979). The upper Bluefield consists of interbedded red, green and variegated shales (many of which are fossiliferous) with thin silts 81 and sands. The sands are highly variable in lithology but most commonly are fine-grained and impure. Several sands were named by Reger (1926). More recent workers (Manspeizer, 1957; McColloch, 1958) have noted that upper Bluefield sandstones are highly localized and cannot be traced laterally for any significant distance. This pattern of discontinuous sandstone distribution is common in deltaic settings, particularly in those that are dominated by fine-grained sediments. Intercalated with the shales, silts and sands are thin marine and nonmarine limestones, coals and dark gray to black shales (Reger, 1926; McColloch, 1957; Manspeizer, 1958). The close association of these lithologies is also diagnostic of deltaic deposition (Visher and others, 1975). Environments of deposition in a deltaic setting include shelf, prodelta, distal bar (also known as delta platform and delta front), and distributary mouth bar in the lower delta plane (subaqueous delta). Environments in the upper delta plane (subaerial delta) include natural levee (overbank splay), distributary channel, beach, interdistributary bay, crevasse splay (bay fill), marsh, and lacustrine delta fill. Barrier islands are sometimes formed at the distal margins of deltaic lobes (Coleman, 1981). Major deltaic depositional environments are summarized in Table 2. INDIAN MILLS SANDSTONE Outcrop 8 (Indian Mills Sandstone) is composed of intercalated sandstone and shale. The sandstones are composed entirely of Type 2 sandstone. Four sand units are present. The lowermost sand, which coarsens upward, is 2.6 meters thick, slightly shaly at its base and 82 TABLE 2 MAJOR DELTAIC DEPOSITIONAL ENVIRONMENTS INTERDIS- Shales and silts; lenticular laminations; TRIBUTARY scattered macro and micro brackish water fauna. BAY: CREVASSE Coarsens upward from shales to sands; sands SPLAY: usually poorly sorted and contain 70-80% quartz; sands contain small-scale cross-beds; sequence may be repeated several times. DISTRIBUTARY Sand fining upward into clays or, sands with one or CHANNEL more fining upward sequences; cross-bedding common; usually scoured lower contact. NATURAL Alternating thin sand, silt, and shale; sands LEVEE : and silts have poor lateral continuity; sands often well sorted; base of sands usually gradational; ripple marked. BEACH: Clean, medium sorted sand with transported organics. DISTRIBU- Sands and silts with small scale cross-bedding TARY MOUTH and high mica content; coarsens upward ; BAR: DISTAL BAR: Coarsening upward sequence of alternating sand, silt and shale laminations; sand and silt become more abundant near top; ripple marks common; faunal content decreases upward. PRODELTA: Finely laminated shale with scattered shells; faunal content decreases upward; grain size increases upward; silt-sand laminations become thicker upward. TIDALLY PRO- Coarsening upward sand with scoured base. DUCED SHELF SANDS SHELF : Marine shales or sediments Indigenous to receiving basin. (after Coleman, 1981) 83 massive in its upper part, and is composed of very fine-grained (0.08-0.09 mm), moderately clean sand. The lower middle sand is 2 meters thick, cross-bedded, and massive. It is composed of clean, fine-grained (0.14mm) sand which shows no grain size trend. The upper 2 sands are each approximately 0.5 meter thick, massive and are composed of very fine- to fine grained sand. These sands are interpreted as distributary mouth bar sands. The outcrop represents stacking of multiple bars which interfinger with prodelta clays. Outcrop Id consists of intercalated shale, silt and sand. Individual laminae are on the order of 2 to 4 cm thick. Maximum grain size is very fine-grained sand. Shale and silt decrease in abundance upward. Quartz percentage is low. Rock fragment and matrix percentages are high. The coarsening upward trend and overall lithology of this unit closely approximates that of distal bars. BRADSHAW SANDSTONE Outcrop Ic consists of finely intercalated sand, silt and shale with most laminae on the order of 2 to 4 cm in thickness. Grain size in the coarse-grained laminae ranges from coarse silt to very fine-grained sand. Shale and silt abundance decreases upward. Quartz percentage is relatively low. Rock fragment and matrix percentages are high. This deposit resembles the coarsening upward sequence of distal bar deposits. The intercalation of sand, silt and shale and overall lithology are typical of distal bar deposits. Outcrop 6 is composed of 2 coarsening upward sequences. The upper sequence grades from fine-grained, matrix-rich (Type 1) sandstone at its 84 base to massive, coarse-grained, clean (Type 2) sandstone in its upper portion. Grain size ranges from coarse silt (0.04mm) in the Type 1 sand in the lower part of the sequence to very fine sand (0.097mm) in the upper part of the sequence. The lower sequence grades from shale at its base to Type 1 sand in its middle part to Type 2 sand in its upper part. Grain size ranges from very coarse silt (0.06mm) in the Type 1 sand to very fine sand (0.08mm) in the Type 2 sand. The lithology and grain size trend of the upper sequence are characteristic of distributary mouth bar deposits. The lithology of the lower sequence is intermediate between upper distal bar and distributary mouth bar deposits. The upper sequence is interpreted as a distributary mouth bar. The lower sequence may represent upper distal bar deposition or deposition in the distal portion of a distributary mouth bar. Outcrop 7 is a coarsening upward sequence from shale and silt at the base to fine-grained (Type 1) massive sandstone at the top. The outcrop is 3.05 meters thick. The upper contact is sharp and the sequence is overlain by green, fosslliferous shale. The overall sequence is similar to that of the distributary mouth bar, but the outcrop is thinner and more fine-grained than typical distributary mouth bar deposits. Outcrop 7 probably represents the distal portion of a distributary mouth bar. BERTHA SANDSTONE Outcrop 5 is composed of 2 strata of Type 2 (coarse-grained) sandstone located at the top and bottom of the outcrop. The Type 2 sand 85 at the base of the outcrop Is coarse-grained, contains abundant clay matrix, and is poorly sorted. Where clay matrix is absent, the sand is cemented by carbonate. The Type 2 sand at the top of the outcrop is coarse-grained, very clean, well-sorted and quartz cemented. The central portion of the outcrop is composed of intercalated calcareous Type 1 sand (very fine-grained, impure), silt and shale. The central portion of the outcrop was largely covered and could not be examined closely. Its general lithology (intercalated sand, silt and shale) can be found in a variety of deltaic environments and so the origin of the sand could not be determined precisely. However, the upper sand provides helpful Information. Its white color and very clean, coarse-grained (medium sand) lithology is rare in the upper Bluefield. Moreover, it is very thin (0.5m) unlike most coarse-grained sands in the deltaic environment. This sand is interpreted as a beach sand developed through reworking of sediments. Deposits of the central part of the outcrop were deposited in relatively shallow water proximal to the beach. Outcrop 4 consists of 4 separate parts. The upper three parts are coarsening upward sequences which range from 2.3 to 3 meters in thickness. These are shaly at their base and coarsen up to massive sand. The sands in the upper sequences are fine-grained (Type 1 sand) and matrix-rich. The lowermost part of outcrop 4 is a fining upward sequence. It is composed of 2 meters of Type 2 (coarse-grained, clean) sandstone at its base which fines upward into silts and shales. The lower contact is sharp and undulatory (scoured). 86 The scoured base and coarse-grained lithology of the base of the lowermost part of outcrop 4 suggests a distributary channel. The channel was abandoned, allowing infilling by finer grained materials. Establishment of an interdistributary bay above the distributary channel resulted in later deposition of crevasse splay deposits represented by the upper sequences of outcrop 4. Outcrop 3b consists of intercalated shale, silt and sand. Individual beds are on the order of 2 to 4 cm thick. Maximum grain size is very fine-grained sand. Shale and silt beds decrease in abundance upward. Quartz percentage is low. Rock fragment and matrix percentages are high. This outcrop is lithologically similar to distal bar deposits. The red color of the outcrop suggests that it was subject to subaerial exposure. Such exposure is characteristic of subaerial natural levee deposits. Outcrop 3b is Interpreted to be a natural levee deposit. GRAHAM SANDSTONE Outcrop 2b, a Type 2 sandstone, is white in color, coarse-grained (medium sand), very clean, well-sorted and quartz-cemented. It is extensively cross-bedded but also contains planar bedding. Crossbedding is generally high angle and unidirectional. Most cross-bedding is planar tabular but accretion bedding and trough cross-bedding are also present. Scour surfaces are present within the sand. Outcrop 2b is interpreted as a braided stream deposit. Trough cross-bedding probably represents channel deposition, while scour surfaces record lateral channel migration. Planar tabular cross-bedding 87 and lateral accretion bedding record downstream bar migration, while planar beds indicate upper flow regime conditions, probably along bar crests. A complex assemblage of these types of bedforms and deposits is characteristic of braided channel deposits (Galloway and Horne, 1983; McCubbin, 1982; Coleman and Prior, 1982). Channel and bar migration within braided channels produces fining upward sequences. Repeated channel and bar migration commonly truncates the earlier sequence, resulting in multiple but often incomplete fining upward sequences (Galloway and Horne, 1983; McCubbin, 1982; Coleman and Prior, 1982). In thin section, outcrop 2b shows two fining upward sequences, perhaps recording channel and bar migration. However, extensive quartz cementation obscures original detrital grain size and so these trends may not be significant. Outcrop lb is composed of Interbedded shale, silt and sand. Individual laminae are on the order of 2 to 4 cm thick. Maximum grain size is very fine-grained sand. Grain size distribution is uniform. Quartz percentage is low. Rock fragment and matrix percentages are high. The unit is calcareous and overlies calcareous and fossiliferous shale. This unit resembles the lower parts of crevasse splay deposits. The absence of a coarser sand, usually found at the top of these units, suggests that outcrop lb was formed at the distal margin of a crevasse splay. CLAYTON SANDSTONE Outcrops la, 3a, and 2a of the Clayton Sandstone are coarsening upward sequences. The outcrops consist of shaly to flaggy sandstone and 88 silt at their bases and coarsen up into massive sandstone. The main sand units range from 1.8 to 4.9 meters in thickness. Sand units on the order of Im thick or less are associated with the main sand bodies. Ripple marks and small scale cross-bedding are commonly present. The sands contain abundant matrix. Grain size in the sands ranges from coarse silt to very fine sand. Associated with the sands are green, black and red shales, some of which are calcareous and/or fossiliferous, and yellow unfossiliferous limestones. Most of these units are interdistributary bay deposits. Some of these may have been subject to restricted or semirestricted conditions. Grain size trends and lithologies are similar to those of crevasse splays. Associated sediments are typical of those of interdistributary bays. Therefore, these sands are interpreted as crevasse splays. Summary Sandstone depositional environments within the upper Bluefield reflect a shift from subaqueous delta deposition in the lower part of the upper Bluefield to subaerial delta deposition in the uppermost Bluefield. Sandstones of the lower part of the upper Bluefield (Indian Mills to Bertha Sandstones) consist largely of distal bar and distributary mouth bar deposits. Uppermost Bluefield sandstones (Bertha to Clayton Sandstones) consist largely of crevasse splay and distributary channel deposits. The upper Bluefield, therefore, is a progradational deltaic sequence with subaerial delta deposits prograding over subaqueous deposits. 89 Interpreted depositlonal environments of upper Bluefield sandstones are summarized in Figure 10. Note that subaerial delta deposits are found as low as the Bertha Sandstone in the northwestern part of the study area but only as low as the Graham Sandstone in the southeastern part of the study area. This indicates that progradation proceeded from northeast to southwest across the study area. DISCUSSION Basin Energy DeWitt and McGrew (1979) suggest that conditions in southeast West Virginia may have shifted from high to lower energy during lower Bluefled time due to "shoaling of the sea and restriction of wave energy along the front of the growing Mauch Chunk-Pennington delta complex in mid-Chester time". Most deposits of the Bluefield Formation below the Droop indicate low energy conditions. Whisonant and Scolaro (1980) studied a stratigraphic section from the middle part of the Bluefield Formation in Mercer County, West Virginia. Primarily on the basis of paleocurrent data, the section was interpreted as having been deposited in a nearshore, tide-dominated environment. No specific tidal range was suggested for the section, however they suggested that tidal currents were oriented north-south. Lower Bluefield shelf sands in the study area are finer-grained than sands deposited in similarly reported environments. Swift and Rice (1984) note that such shelf sands are generally not formed by fair weather processes (currents) but rather by large storms (hurricanes). Most documented shelf sands from the Cretaceous mid-continent area SOUTHWEST NORTHEAST SECTIONS 1 5 2 12 6 A lA 8 13 3 9 7 10 11 CLAYTON SANDSTONE CUVASU cacvASsi CAfTASSt SPLAT SPUT SPUT SUBAERIAL GRAHAM SANDSTONE CtCVASSI D&AIOCD SPLAT OtAIOfCL DELTAIC BERTHA cuvast SPUT SANDSTONE DtACI êmà LCVCt DtSTBIS* OTAKT ounitL BRADSHAW OISTUD* DISTUA- SANDSTONE DISTAL bTAAT UTAtT lAD N0L*IV SUBAQUEOUSncvn AAA la INDIAN DELTAIC OlSTtlB* MILLS DISTAL VTAITAAl HDtmi SANDSTONE AAH DROOP SANDSTONE AAJUliei lAJlAUt AAAAIEA tSUlfD ISLAND ISLAND COASTAL LOWER SANDSTONES tmj SMLP SMtir un SAAD SAAO SHELF Figure 10: Bluefield sandstone depositional environments VO o 91 referred to by Swift and Rice (1984) are from the north-south trending, east-facing shelf and, therefore, were subject to hurricanes. During the Late Mississippian the Appalachian basin was a south and west facing basin and so storm intensities may have been lower than those of the east-facing Cretaceous shelf (i.e., they would not have been subject to the direct impact of hurricanes). The finer-grained nature of the lower Bluefield sandstones, therefore, does not necessarily indicate that normal (fair weather) energy conditions were low. The coarse-grained, clean, cross-bedded lithology of the Droop Sandstone suggests that basin energy was high at least through deposition of the middle Bluefield. Both wave and current energy were probably important contributors. The preponderence of shales and fine-grained, impure lithology of the sandstones in the upper Bluefield suggests that basin energy was low (deWitt and McGrew, 1979). Deltaic sands in high energy environments are typically thicker, cleaner and more laterally extensive than those found in the upper Bluefield. Conclusions The Droop Sandstone was likely deposited as a barrier island complex fronting a delta complex as it prograded over the lower Bluefield shelf sediments. The delta was deposited into esturine and/or lagoonal environments which were protected by the barrier island complex. Basin energy was largely absorbed by the barrier island complex. Wave and tidal energy were lower in the back barrier area allowlng less winnowing of fines and less concentration of coarse-grained materials resulting in the largely fine-grained shaly 92 nature of upper Bluefleld sands. Coarse-grained, clean (orthoquartzite) sands in the uppermost part of the Bluefield were produced by fluvial processes (subaerial delta). 93 SUMMARY The Bluefield Formation represents deposition transitional between the marine Greenbrier Limestone below and the shallow marine to deltaic upper Mauch Chunk sediments above. Most lower Bluefield units are laterally continuous and readily identifiable. Upper Bluefield units are laterally discontinuous. The Droop Sandstone, located at the transition between the lower and upper Bluefield, is a sheet-like, coarse, white, cross-bedded unit of distinctive lithology (orthoquartzite) which can serve as a marker unit separating the upper and lower Bluefield in the study area. Sandstones within the Bluefield range from greenish-gray to buff, fine-grained, calcareous varieties in the lower part to greenish-gray and reddish-brown, fine- to very fine-grained or, rarely, coarse, white, cross-bedded varieties in its upper part. Bluefield sandstones fall into two groups. Types 1 and 2. Type 1 sands are thin, fine-grained, ripple-marked, and coarsen upward in outcrop. Quartz abundance is low, averaging 55.8%, and they are rich in rock fragments and matrix. Type 2 sands are relatively thick, coarse-grained, well-sorted and cross-bedded and are quartz-rich (averaging 83.8%). Diagenetic alteration of Type 1 sands was dominated by mechanical compaction. Other diagenetic events include carbonate, quartz, pyrite, hematite and clay mineral authigenesis, intergranular pressure solution, stylolitization and fracturing. All primary porosity was occluded in Type 1 sandstones. Minor secondary moldic and fracture porosity is 94 present. Quartz authigenesis, accompanied by intergranular pressure solution and stylolitization, was the principal diagenetic process in Type 2 sandstones. Quartz authigenesis did not totally occlude primary intergranular porosity. Secondary moldic porosity was formed by the solution of feldspars (moldic porosity) and by fracturing. Carbonate and clay mineral authigenesis and mechanical compaction also occurred in Type 2 sandstones. Lower Bluefield units consist of marine limestone, calcareous shale and thin carbonate-cemented shelf sands deposited in a shallow marine setting. The Droop Sandstone was deposited as a prograding barrier island complex. Uplift of a largely metamorphic source to the east of the study area caused large volumes of detritus to be eroded and transported to the area. Upper Bluefield units reflect encroachment into the area of prograding deltaic environments in which red and green shales and sandstones, minor coals and limestones were deposited. Sandstones found within the upper Bluefield include distal bar, distributary mouth bar, beach, crevasse splay, natural levee and distributary channel deposits. 95 REFERENCES CITED Arkle, T., Beissel, D.R., Larese, R.E., Nuhfer, E.S., Patchen, D.G., Smosna, R.A., Gillespie, W.H., Lund, R., Norton, L.W., and Pfefferkorn, H.W., 1979, The Mississippian and Pennsylvanian (Carboniferious) Systems in the United States - West Virginia and Maryland: United States Geological Survey Professional Paper 1110-D, 35p. 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Swift, D.J.P., and Rice, D.D., 1984, Sand bodies on muddy shelves: a model for sedimentation in the Western Interior Seaway, North America: in Tillman, R.W., and Siemers, C.T. (eds), Slliciclastlc Shelf Sediments : Society of Economic Paleontologists and Mineralogists Special Publication No. 34, p. 43-62. Swires, C.J., 1977, Source area of Mauch Chunk sediments in the Hurricane Ridge Syncline in southeastern West Virginia: unpublished M.S. thesis. University of Akron, 41p. Visher, G.S., Ekebafe, S.B., and Rennlson, J., 1975, The Coffeyville Format (Pennsylvanian) of northeastern Oklahoma, a model for an epeiric sea delta: in Broussard, M. (ed). Deltas, Models for Exploration: Houston Geological Society, p. 381-398. Walker, T.R., 1974, Formation of red beds in moist tropical climates; an hypothesis: Geological Society of America Bulletin, v.85, p. 633-638. Walker, T.R., 1976, Diagenetic Origin of Continental Red Beds:, in Falke, H. (ed). The Continental Permian in Central, West and South Europe, D. Reidel, Dordrecht-Holland, p. 240-282. Wanless, H.R., 1979, Limestone response to stress: Pressure solution and dolomltization: Journal of Sedimentary Petrology, v. 49, p. 437-462. Weyl, P.K., 1959, Pressure solution and the force of crystallization: Journal of Geophysical Research, v. 64, p. 2001-2005. Whisonant, R.C., and Scolaro, R.J., 1979, Tide dominated coastal environments in the Mississlppian Bluefleld Formation of eastern West Virginia: in Tanner, W.F. (ed). Shorelines, Past and Present : Proceedings of the Fifth Symposium on Coastal Sedlmentology, Florida State University, Tallahassee, p. 593-637. Yeh, H., and Savin, S.M., 1973, The mechanism of burial diagenetic reactions in argillaceous sediments. 3. Oxygen isotope evidence (abs): American Geophysical Union Transactions, v. 54, p. 508. 99 Youse, A.C., 1964, Gas producing zones of Greenbrier (Mlssissipplan) Limestone, southern West Virginia and eastern Kentucky: Bulletin of the American Association of Petroleum Geologists, v. 48, p. 465-486. 100 APPENDIX A; MEASURED SECTIONS GENERAL Named units in the Bluefield are largely those of Reger (1926). More recent workers have found that most of the units named by Reger, particularly in the upper part of the Bluefield, cannot be traced laterally for significant distances. Manspeizer (1958) and McColloch (1957) combined many of these units into various "intervals". For example, the Bertha Sandstone, Limestone, and Shale were combined into the "Bertha Interval". These "intervals" generally can be traced laterally and can be identified at most outcrops of the Bluefield Formation, whereas its individual components (Bertha sandstone, Bertha Limestone etc.) cannot be so identified. The names given to the sandstones by Reger (1926) are used in this report. Most sample sites chosen in this study were those identified by Reger (1926). 101 RED SULPHUR SPRINGS SECTION Location This section begins just north of the town of Ballard in Monroe County, West Virginia, and continues, in descending stratigraphic order, northward to Red Sulphur Springs along state road 12. Reger (1926) measured this section along a road (which is no longer in use) parallel to state road 12. Unit Lithologies Outcrop la - Clayton Sandstone Thickness Total (meters) Sandstone, reddish-brown to greenish-brown, 3.66 6.15 fine-grained, massive to ripple-marked, slightly flaggy in parts, becomes shaly at top; upper contact sharp to narrowly transitional Shale, green, partly covered 0.91 2.49 Sandstone, green, fine-grained, massive 0.76 1.58 Shale, covered 0.36 0.82 Sandstone, green, fine-grained, flaggy to 0.46 0.46 shaly, ripple-marked; plant fossils present; lower contact sharp with underlying shales Outcrop lb - Graham Sandstone Thickness Total (meters) Sandstone, green, very fine-grained, shaly, 2.90 2.90 becomes more shaly in center of section, ripple-marked; upper contact covered, lower contact narrowly transitional; underlying shales are sandy and fosslliferous 102 Outcrop le - Bradshaw Sandstone Thickness Total (meters) Sandstone, green, fine-grained, massive in 1.49 3.93 upper and lower parts, shaly to flaggy and ripple-marked in center; upper contact covered Sandstone, green, fine-grained, shaly to 2.44 2.44 flaggy, ripple-marked; lower contact covered Outcrop Id - Indian Mills Sandstone Thickness Total (meters) Sandstone, green, fine-grained, shaly at 1.52 3.78 bottom, grades upward into massive sandstone at top; upper contact covered Sandstone, green, fine- to very fine-grained, 2.26 2.26 lower 1.83 meters shaly to very shaly and ripple- marked, upper 0.43 meters massive; lower contact transitional with underlying shales 103 BUCK SECTION Location The village of Buck is located in Summers County, West Virginia, on county road 14. The Clayton and Graham Sandstones are exposed in the vicinity of Buck and are included in this section. The Clayton Sandstone is found on the north side of county road 14, 1.5 miles west of Buck. Reger (1926) described this outcrop as "25 feet thick and shaly". The Graham Sandstone is found in the bed of Wolf Creek just east of Buck on the south side of county road 14. Reger described this outcrop as "coarse, massive" and "30 to 40 feet thick". Unit Lithologies Outcrop 2a - Clayton Sandstone Thickness Total (meters) Sandstone, reddish-brown, fine-grained, 4.48 7.16 massive, medium-bedded, ripple-marked; minor shale lenses present; upper part becomes shaly and grades into overlying red shales Shale, red 1.22 2.28 Limestone, yellow 0.15 1.06 Sandstone, reddish-brown, fine-grained, 0.91 0.91 massive; sharp bounding contacts; underlying units consist of red shales Outcrop 2b - Graham Sandstone Thickness Total (meters) Sandstone (orthoquartzite), medium- to coarse- 14.02 14.02 grained, white to buff; uppermost portion horizontally bedded, middle portion extensively cross-bedded; cross-beds are large scale (up to 2 feet) and generally high-angle (up to 25 degrees), and are apparently unidirectional; planar cross-bedding most abundant; lowermost portion is calcareous and cross-bedded and contains lenses and lobes of non-calcareous orthoquartzite 104 TALCOTT #1 SECTION Location This is the Talcott Section of Reger (1926) and is located just east of the town of Talcott in Summers County, West Virginia, on state road 12. It begins just north of the eastern portal of Big Bend Tunnel and continues, in descending stratigraphic order, northeast toward Talcott. Unit Lithologies Outcrop 3a - Clayton Sandstone Thickness Total (meters) Sandstone, reddish-brown, fine-grained, 1.83 7.61 massive becoming flaggy at top; upper contact sharp to narrowly transitional with overlying red shales Shale, green 0.91 5.78 Sandstone, green, massive 0.15 4.87 Shale, green, calcareous, fossiliferous 0.15 4.72 Shale, reddish-brown 1.22 4.57 Sandstone, reddish-brown, fine-grained, upper 3.35 3.35 two thirds massive, lower third shaly to very shaly; lower contact narrowly transitional with underlying yellow limestone and gray calcareous shale Outcrop 3b - Bertha Sandstone Thickness Total (meters) Sandstone, reddish-brown, fine-grained, 2.44 2.44 ripple-marked; lower shaly part coarsens upward to flaggy upper part; upper and lower contacts covered 105 MARIE SECTION Location This outcrop is located southeast of the village of Marie in Monroe County, West Virginia, on county road 19. Reger (1926) described the outcrop as "shaly at top, massive at base" and 30 feet thick. Unit Lithology Outcrop 4 - Bertha Sandstone Thickness Total (meters) Sandstone, green, fine-grained, shale at base 2.74 11.58 grading up to massive sandstone in upper part; upper contact sharp with overlying shales Sandstone, green, fine-grained, shaly at base, 1.16 8.84 grades up to flaggy sandstone Shale, dark gray 0.82 7.68 Shale, green, upper 0.38 meters consists of 1.68 6.86 green, flaggy to massive sandstone Sandstone, green, fine- to very fine-grained, 1.37 5.18 upper and lower portions shaly, center part flaggy to massive Shale, green; mostly covered 1.83 3.81 Sandstone, brown becoming greenish toward 1.98 1.98 upper part, fine- to medium-grained, massive; more massive at base and fines upward; shaly zone in center; lower contact sharp and wavy with underlying shales and yellow limestone 106 BERTHA SECTION Location Reger (1926) first described this section on what is now county road 33 near the village of Bertha in Summers County, West Virginia. Bertha is now covered by water of the Bluestone Reservoir. The outcrop is located on county road 33 west of its juncture with county road 14/2 and west of and below the Bluestone Conference Center. This is the type section for the Bertha Sandstone. Reger (1926) described the outcrop as being "shaly and 45 feet thick". Unit Lithology Outcrop 5 - Bertha Sandstone Thickness Total (meters) Sandstone, white to buff with iron stains, 0.30 10.81 medium to coarse-grained, massive; sharp bounding contacts; overlain by shales Shale, green, mostly covered 0.76 10.51 Sandstone, green, fine-grained, massive and 5.33 9.75 ripple-marked; calcareous; intercalated with green shale, most of which is covered Sandstone, green, fine-grained, flaggy to 0.61 4.42 shaly Sandstone, green, fine- to medium-grained, 0.46 3.81 cross-bedded Sandstone, green, fine-grained, shaly to 0.91 3.35 flaggy; intercalated with green shale Sandstone, green to dark gray, fine- to very 1.92 2.44 fine-grained, very shaly; coarsens upward from lower shaly part into coarser upper part Sandstone, greenish-brown, medium-grained, 0.52 0.52 massive; calcareous; underlying shales are covered BIG BEND SECTION Location This outcrop is located in Summers County, West Virginia, just east of the mouth of Spruce Run, and just northeast of the juncture of state road 12 and county road 29, on the southeast side of county road 29. Reger (1926) described this outcrop as shaly and 50 feet thick. Unit Lithology Outcrop 6 - Bradshaw Sandstone Thickness Total (meters) Sandstone, green, fine- to medium-grained, 2.44 10.81 massive with minor shale lenses; upper contact and overlying sediments eroded Sandstone, green, fine-grained, very shaly at 2.71 8.37 base coarsening upward into flaggy sandstone Sandstone, gray, fine- to medium-grained; 1.46 5.66 cross-bedding present and especially prominant in upper part; ripple-marks also common Shale, dark green to dark gray, fisile 0.27 4.20 Sandstone, greenish-brown, fine-grained, with 1.34 3.93 shaly portion in center Sandstone, green, fine-grained, shaly to 1.22 2.59 flaggy; partly covered Sandstone, gray to green to brown, fine- 1.37 1.37 grained, ripple-marked; contains brown carbonate interbeds, lower contact is sharp; underlying shales are green, gray and red and nodular and contain coal seams 108 PENCE SPRINGS SECTION Location This outcrop is located in Summers County, West Virginia, on county road 3/18 just northeast of the juncture of county road 3/18 and state road 12. This locality is the Pence Springs Section of Reger (1926). Reger described the Bradshaw Sandstone here as being green, hard and 10 feet thick. Unit Lithology Outcrop 7 - Bradshaw Sqandstone Thickness Total (meters) Sandstone, green, fine-grained, massive, 1.22 3.05 ripple-marked; minor shale lenses; upper contact sharp with overlying green, calcareous, fossiliferous shale Sandstone, green, fine-grained, shaly to 1.83 1.83 flaggy; contains one thin massive sand layer; lower contact transitional with underlying green, black and gray shales 109 ROCK CAMP SECTION Location This outcrop is located in Monroe County, West Virginia, on the north side of U.S. Route 219, approximately 0.1 miles north of the junction of U.S. Route 219 and county road 29 at the town of Rock Camp. Reger (1926) described this outcrop as "gray, coarse, massive, and hard". Unit Lithology Outcrop 8 - Indian Mills Sandstone Thickness Total (meters) Sandstone, green, fine-grained, massive; sharp 0.46 7.71 bounding contacts; overlying rocks are covered Shale, green, largely covered 0.67 7.25 Sandstone, green, fine-grained, massive; sharp 0.61 6.58 bounding contacts Shale, green, sandy; largely covered 0.64 5.97 Covered 1.28 5.33 Sandstone, green, fine-grained; low angle 1.52 4.05 cross-bedding; becomes shaly in center; sharp bounding contacts Shale, green, partly covered; coal seam at top 1.01 2.53 Sandstone, green shaly at base coarsening 1.52 1.52 upward into fine-grained sand; sharp lower contact; underlying sediments are shale with thin sand stringers lio TALCOTT #2 SECTION Location This outcrop is located in Summers County, West Virginia, just southeast of the town of Talcott, on the south side of county road 15/2 approximately 0.25 miles east of the juncture of county roads 17 and 15/2. The outcrop was measured along a private road which ascends Wind Creek Mountain. Unit Lithology Outcrop 9 - Droop Sandstone Thickness Total (meters) Sandstone (orthoquartzite), white to buff, 21.34 21.34 weathers buff to brown; medium-grained, friable; lower part characterized by abundant high angle (up to 25 degrees), large-scale (up to 2 feet), trough and minor planar cross-bedding; upper part characterized by low-angle, small-scale cross-bedding, horizontal bedding and minor ripple-marks; lower contact sharp and undulatory with underlying greenish-brown, calcareous, highly fossiliferous shale Ill ALDERSON SECTION Location This outcrop is located in Monroe County, West Virginia, southwest of the town of Alderson on the north side of county road 1 approximately 0.3 miles east of the juncture of county road 1 and state road 3. Reger (1926) noted that the exposure "makes a great white cliff 80 feet thick". Unit Lithology Outcrop 10 - Droop Sandstone Thickness Total (meters) Covered; includes Droop float 3.66 24.54 Sandstone (orthoquartzite), white to buff, 20.88 20.88 weathers buff to brown; medium-grained, friable; lower part characterized by abundant high angle (up to 25 degrees), large-scale (up to 2 feet), trough and minor planar cross-bedding; upper part characterized by low angle, small-scale, cross-bedding, horizontal bedding and minor ripple-marks; upper contact covered, lower contact sharp and wavy 112 ALTA SECTION Location This outcrop is located in Greenbrier County, West Virginia, on the southeast side of U.S. Route 60, just northeast of the bridge which spans Interstate 64, and 1.5 miles northwest of the town of Alta. Price and Heck (1939) described this outcrop as white, massive, cross-bedded and 50 feet thick. Unit Lithology Outcrop 11 - Droop Sandstone Thickness Total (meters) Sandstone (orthoquartzite), white to buff, 13.72 13.72 weathers buff to brown; medium-grained, friable; lower part characterized by abundant high angle (up to 25 degrees), large-scale (up to 2 feet), trough and minor planar cross-bedding; upper part characterized by low angle, small-scale cross-bedding, horizontal bedding and minor ripple-marks; upper and lower contacts covered 113 ASSURANCE SECTION Location This outcrop is located in Monroe County, West Virginia, approximately 2 miles south of the town of Greenville, on the north side of county road 25/4. Reger (1926) described this outcrop as "being massive but having some green shale in the upper portion, the entire thickness being 35 feet". Unit Lithology Outcrop 12 - Webster Springs Sandstone Thickness Total (meters) Sandstone, green, shaly to flaggy, ripple- 1.22 7.32 marked; upper contact covered Sandstone, greenish-brown, shaly, ripple- 2.44 6.1 marked; thin shale seam at top Sandstone, greenish-brown, fine-grained, 1.68 3.66 medium-bedded to flaggy; contains a few shale lenses; cross-bedded at base, fines upward Sandstone, greenish-brown to buff, cross- 1.98 1.98 bedded; lower contact covered 114 WAYSIDE SECTION Location This outcrop Is located In Monroe County, West Virginia, on the north side of county road 7 approximately 2 miles northeast of the village of Wayside. Reger (1926) described this outcrop as "15 feet thick, calcareous and shaly". Unit Lithology Outcrop 13 - Webster Springs Sandstone Thickness Total (meters) Sandstone, partly gray and calcareous and 1.75 10.37 partly greenish-brown; fine-grained, massive at top becoming shaly at base; upper and lower contacts sharp; overlying sediments largely calcareous shales Shale, yellow, calcareous 2.29 8.62 Sandstone, greenish-brown, fine-grained, 0.23 6.33 massive Shale, yellow, calcareous 3.66 6.10 Sandstone, greenish-brown, fine-grained, 2.44 2.44 upper part massive, lower part massive to slightly shaly, central part shaly; ripple- marks present In shaly part; upper contact with shale sharp; lower contact covered 115 GREENVILLE SECTION Location Approximately 2 miles west of the town of Greenville in Monroe County, West Virginia, a road cut on the north side of state road 122 exposes a sandstone in the lower part of the Bluefield Formation. This sandstone may be equivalent to the Edray Sandstone of Reger (1926). Unit Lithology Outcrop 14 - Edray Sandstone Thickness Total (meters) Sandstone, green, very fine-grained, very 4.22 6.86 shaly to flaggy; calcareous; upper contact gradational; overlain by shale Sandstone, gray, very fine-grained, ripple- 2.44 2.44 marked; calcareous; lower contact covered 116 APPENDIX Bl: POINT COUNT DATA Type 1 Sandstones Sample Quartz MRFs SRFs Matrix Feld- Pore Carbon- Other Number spar Space ate Ka8 56.0 27.0 1.3 6.0 3.7 0.0 0.3 5.7 Ka2 46.7 17.3 16.7 19.3 T 0.0 0.0 T Avg. 51.3 22.2 9.0 12.6 1.8 0.0 0.1 2.8 Fll 49.0 18.0 T 26.0 1.0 0.0 0.0 6.0 F6 64.7 16.0 T 15.0 1.3 0.0 0.0 3.0 Avg. 56.8 17.0 T 20.5 1.1 0.0 0.0 4.5 B3 59.0 23.7 T 10.3 T 0.0 0.0 7.0 B7c 43.3 21.0 T 28.7 T 0.0 0.0 7.0 Avg. 51.1 22.4 T 19.5 T 0.0 0.0 7.0 Kbl 46.3 23.0 6.3 18.3 0.7 0.0 1.3 4.1 Kb2 51.3 25.0 0.3 ?? 13.0 0.3 1.0 5.7 3.4 Avg. 48.8 24.0 3.3 15.6 0.5 0.5 3.5 3.8 L3 46.0 25.3 T 19.3 1.3 0.3 0.0 7.8 LI 60.7 19.7 T 10.3 T 1.0 0.0 8.3 Avg. 53.3 22.5 T 14.8 0.6 0.6 0.0 8.0 Ke6 48.0 10.7 9.7 19.3 3.7 0.0 6.0 2.6 Ke4 65.3 18.3 T 11.7 1.3 0.3 0.0 3.1 Avg. 56.6 14.5 4.8 15.5 2.5 0.1 3.0 2.8 V4 67.7 19.3 1.0 2.7 1.0 0.0 4.7 3.6 V6 58.7 20.7 1.3 7.3 1.0 0.7 5.7 4.6 V8 42.3 13.0 30.7 6.7 0.3 0.0 2.7 4.3 Avg. 56.2 17.7 11.0 5.6 0.8 0.2 4.4 4.2 Kc5 45.7 2.0 17.0 26.3 T 0.7 4.3 4.0 Kc2 56.3 22.3 0.7 19.0 1.0 0.0 0.0 0.7 Avg. 51.0 12.1 8.8 22.6 0.5 0.3 2.2 2.3 S7 58.3 13.3 T 7.3 0.3 0.0 15.7 5.1 S3 66.0 24.3 0.3 2.7 3.0 0.0 2.3 1.4 S2 62.3 25.0 0.3 5.0 1.3 7 ? 6.1 SI 60.3 21.0 0.7 9.7 5.3 0.3 2.3 0.4 Avg. 61.7 20.9 0.3 6.2 2.5 0.1 5.1 3.2 117 J5 41.0 T 0.0 7.0 2.0 0.0 47.7 2.3 J4 50.0 0.3 0.0 0.0 0.3 ? 48.3 1.0 J3 71.7 7.3 0.0 16.7 T 0.7 0.0 3.6 J2b 71.0 4.7 0.0 2.3 1.0 0.0 18.0 3.0 Ja4 51.0 23.0 7.0 6.3 0.7 1.7 8.3 2.0 Ja3b 58.0 6.7 0.0 13.7 T 0.0 20.0 1.6 Ja2 49.7 25.0 0.0 8.0 T 0.0 4.0 13.3 Avg. 56.1 9.6 1.0 7.7 0.6 0.3 20.9 3.8 R4 67.7 7.0 0.7 18.7 0.7 0.3 2.3 2.6 R3 62.0 18.7 0.0 14.3 0.7 0.0 2.3 2.0 R1 67.0 16.7 0.7 7.6 1.3 0.0 5.3 1.4 Avg. 65.6 14.1 0.5 13.5 0.9 0.1 3.3 2.0 Type 2 Sandstones Cla 90.3 2.3 0.7 4.0 0.3 1.7 0.0 . 0.7 C3 79.7 T T 17.3 T 3.0 0.0 T C4 87.3 1.3 T 6.0 0.3 5.0 0.0 T C5 85.0 1.3 6.0 3.3 T 4.3 0.0 T C9 72.0 7.3 2.3 13.0 1.0 3.7 0.0 0.7 CIO 75.0 10.3 3.3 8.3 0.3 1.3 0.0 1.3 Avg. 81.6 3.8 2.0 8.6 0.8 3.2 0.0 0.4 D2 93.0 0.7 2.0 0.7 0.3 3.3 0.0 T D3cl 95.7 1.3 T 0.7 0.0 2.3 0.0 T D6 95.7 T T 0.3 0.0 4.0 0.0 T D9 95.3 T 0.0 1.7 0.0 2.7 0.3 0.3 D20 86.0 T 0.0 8.7 0.0 5.0 0.3 T D18 72.3 T T 3.7 0.0 4.3 19.7 T D17 54.3 0.3 T T 0.7 0.0 44.7 T D16 92.3 0.7 0.3 T 0.0 1.0 5.7 T Avg. 85.6 0.4 0.3 2.0 0.1 2.8 8.8 T M16 76.3 7.7 3.0 9.0 0.3 3.7 0.0 T MU 78.7 1.0 1.3 15.0 0.3 2.7 0.0 1.0 MIO 84.0 7.0 2.0 1.3 T 4.7 0.0 1.0 M7 80.0 0.3 1.3 10.0 0.7 7.0 0.0 0.7 M5b 89.7 3.0 1.3 1.7 1.0 3.0 0.0 0.3 M4 87.3 2.3 0.7 2.3 2.0 5.0 0.0 0.3 M3 79.7 9.3 T 5.3 0.7 5.0 0.0 T Avg. 82.2 4.4 1.4 6.4 0.7 4.4 0.0 0.5 DB67 87.0 T 3.0 5.0 0.0 5.0 0.0 T DB49 87.3 T 4.3 8.0 0.0 T 0.0 T DB35 94.3 0.7 T 0.3 0.0 4.3 0.0 0.3 DB20 89.7 3.0 1.0 1.7 0.0 4.7 0.0 T DB12 87.7 2.3 0.3 1.7 0.0 8.0 0.0 T DBl 94.0 0.3 T 2.0 0.0 3.7 0.0 T Avg. 90.0 1.0 1.4 3.1 0.0 4.3 0.0 0.1 118 DD40 89.3 T 2.3 5.0 0.0 3.3 0.0 T DD26 93.7 1.7 1.7 0.7 0.0 2.3 0.0 T DD20 94.7 T 2.7 1.3 0.0 1.3 0.0 T DD8 94.3 0.7 T 0.3 0.0 4.3 0.0 0.3 DD4 91.0 1.3 T 2.3 0.0 5.3 0.0 T Avg. 92.6 0.7 1.3 1.9 0.0 3.3 0.0 0.1 Mixed Type 1 and Type 2 Sandstones 116 61.3 24.3 0.7 8.7 0.7 1.0 0.0 3.3 114 64.0 13.3 T 21.7 T T T 1.0 17 68.3 4.3 4.0 20.7 0.3 T 0.0 2.3 16 78.3 7.0 3.0 9.7 0.7 1.3 0.0 T 14 87.0 T 2.0 3.0 T 5.3 0.0 0.7 Avg. 71.8 9.8 1.9 12.8 0.3 1.5 T 1.5 A19b 55.3 26.3 4.0 10.7 T 0.3 T 3.3 A16 61.3 23.7 0.7 12.0 0.7 T 0.0 1.7 A13 86.0 5.7 1.4 5.5 T T 0.0 1.5 All 80.3 11.0 4.7 2.7 T T 0.0 1.3 A8 56.0 30.0 T 9.3 1.7 0.3 T 2.7 A2 78.0 14.7 1.0 2.0 0.3 2.7 0.0 1.3 Avg. 70.3 18.2 1.9 6.7 0.4 0.6 T 1.9 H13 92.3 0.7 3.3 2.3 0.0 1.0 0.0 0.3 HU 55.3 21.7 3.0 14.7 0.7 1.3 T 3.3 H7 48.3 18.3 0.3 8.7 0.7 0.0 22.0 1.7 H4 49.3 24.3 5.3 6.7 1.0 0.3 11.0 2.0 H3 52.0 11.3 1.0 10.7 T T 21.7 3.3 HI 56.3 14.7 1.0 9.3 0.7 2.7 15.0 0.3 Avg. 58.9 15.2 2.3 8.7 0.5 0.9 11.6 1.8 APPENDIX B2 GRAIN SIZE DATA Sandstone Sample Mean long Number axis diameter (in mm) Clayton Ka8 .07 ka2 .0441 Fll .043 F6 .038 B3 .042 B7c .081 Graham Kbl .05 Kb2 .0626 D2 .256 D3cl .2225 D6 .2669 D9 .2757 D20 .2505 D18 .2191 D17 .2808 D16 .2693 Bertha H13 .2023 H9 .0503 H7 .0577 H4 .0781 H3 .0470 HI .1504 116 .0594 114 .0557 17 .0645 16 .0847 15 .0954 14 .1281 L3 .0474 LI .0328 Bradshaw Ke6 .0764 Ke4 .0456 V4 .0688 V5 .0636 V6 .0657 V8 .0378 120 A19b .0464 A17 .0357 A16 .0559 A13 .0826 A8 .0551 A7 .0652 A2 .0974 Indian Mills Kc5 .0366 Kc2 .0562 Cla .1198 C3 .1347 C4 .1419 C5 .1391 C9 .0933 CIO .0783 Droop M16 .0923 Mil .1131 MIO .1095 M7 .153 M5b .1512 M4 .1553 M3 .1608 DB67 .1824 DB49 .204 DB35 .2093 DB20 .2403 DB12 .1516 DBl .3426 DD40 .19 DD26 .209 DD20 .24 DD8 .1872 DD4 .2115 Webster J5 .0494 Springs J4 .0478 J3 .0590 J2b .0528 JA4 .0628 JA3a .0419 JA3b .0392 JA2 .0309 S7 .0645 S3 .0768 S2 .0694 SI .0647 Edray R4 .0390 R3 .0371 R1 .0615