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Decarboxylative and dehydrative coupling of dienoic acids and pentadienyl alcohols to form 1,3,6,8-tetraenes

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dc.contributor.authorAbu Deiab, Ghina’a I.
dc.contributor.authorAl-Huniti, Mohammed H.
dc.contributor.authorHyatt, I. F. Dempsey
dc.contributor.authorNagy, Emma E.
dc.contributor.authorGettys, Kristen E.
dc.contributor.authorSayed, Sommayah S.
dc.contributor.authorJoliat, Christine M.
dc.contributor.authorDaniel, Paige E.
dc.contributor.authorVummalaneni, Rupa M.
dc.contributor.authorMorehead, Andrew T. Jr.
dc.contributor.authorSargent, Andrew L.
dc.contributor.authorCroatt, Mitchell P.
dc.date.accessioned2020-04-17T16:14:38Z
dc.date.available2020-04-17T16:14:38Z
dc.date.issued2017-02-28
dc.description.abstractDienoic acids and pentadienyl alcohols are coupled in a decarboxylative and dehydrative manner at ambient temperature using Pd(0) catalysis to generate 1,3,6,8-tetraenes. Contrary to related decarboxylative coupling reactions, an anion-stabilizing group is not required adjacent to the carboxyl group. Of mechanistic importance, it appears that both the diene of the acid and the diene of the alcohol are required for this reaction. To further understand this reaction, substitutions at every unique position of both cou- pling partners was examined and two potential mechanisms are presented.en_US
dc.identifier.doi10.3762/bjoc.13.41
dc.identifier.urihttp://hdl.handle.net/10342/8171
dc.titleDecarboxylative and dehydrative coupling of dienoic acids and pentadienyl alcohols to form 1,3,6,8-tetraenesen_US
dc.typeArticleen_US
ecu.journal.issue1en_US
ecu.journal.nameBeilstein Journal of Organic Chemistryen_US
ecu.journal.pages384-392en_US
ecu.journal.volume13en_US

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